A reliable and sensitive analytical platform is proposed for the assessment of pig exposure to mycotoxins through the consumption of commercial feed. A total of 48 naturally contaminated feed and 55 urine samples collected from eight Spanish farms were analyzed using a fast and simple methodology based on solid-liquid extraction (SLE) or liquid-liquid extraction (LLE) and dispersive liquid-liquid microextraction (DLLME). High-performance liquid chromatography coupled to tandem mass spectrometry (HPLC-MS/MS) was used for the targeted analysis of 27 mycotoxins from different families in both matrices achieving limits of quantification in a range of 0.
View Article and Find Full Text PDFThe reuse of treated wastewater for agricultural irrigation has enlarged the risk of pharmaceutical compound accumulation in soil and their potential translocation to crops. Therefore, it is necessary to apply effective techniques to remove these pollutants from soil. This work was aimed to study the effectiveness of two advance oxidation processes (photocatalysis and ozonation) in the degradation of carbamazepine (CBZ) residues in three different soil matrices.
View Article and Find Full Text PDFReusing reclaimed water for crop irrigation can mitigate water scarcity in agriculture; however, contaminants such as pharmaceuticals and pesticides in wastewater pose risks. This study investigated the impact of a coupled bio-solar photocatalytic treatment on the reclamation of water polluted with seven pharmaceuticals and seven pesticides for irrigation of two tomato crop cycles. Pollutant residues were removed using natural sunlight and TiO/NaSO in a pilot plant located in Murcia, Spain.
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