The large number of tires produced annually demands new recycling methods. A key challenge associated with recycling elastomers is their crosslinking structure that prevents fusion. It is possible to reverse crosslinking through a process called devulcanization.
View Article and Find Full Text PDFIn accordance with the Circular Economy Package of the European directive, the Spanish government compels manufacturers of plastic bags to include into their products a minimum of 70% of polyethylene (PE) waste. Following this mandate can be challenging and requires a deep knowledge of the alterations produced by the recycling in the main components of a plastic bag film: lineal low-density polyethylene (LLDPE), the LLDPE recycled post-industry, generated as waste from an industrial process (rLLDPE) and the PE recycled from post-consumer use (rPE), that has been picked up, cleaned, and reprocessed. This study provides insight in the macro and microstructural changes produced by several cycles of recycling in these materials.
View Article and Find Full Text PDFThe environmental degradation of the films used in packaging is a key factor in their commercial use. Industrial and academic research is aimed at obtaining materials that have degradation features that ensure their eco-sustainability but, at the same time, preserve their use properties during storage and distribution periods. This study analyzes the degradability behavior over time of commercial packaging that meets the requirements of the UNE 13432 standard and the prEN 17427 (2020) home composting certification requirements under standard storage conditions.
View Article and Find Full Text PDFEthylene propylene diene monomer (EPDM) is one of the most used polymers in the world. It is an elastomer, which means that the existing cross-linking between the main chains of the polymer created during the vulcanization process makes its recycling difficult. In this paper, a possible solution to this issue is studied.
View Article and Find Full Text PDFIn this work, ground tire rubber (GTR) was thermo-mechanically treated in the presence of styrene-butadiene-styrene (SBS) copolymers. During preliminary investigation, the effects of different SBS copolymer grades, the variable content of SBS copolymer on the Mooney viscosity, and the thermal and mechanical properties of modified GTR were determined. Subsequently, GTR modified by SBS copolymer and cross-linking agents (sulfur-based system and dicumyl peroxide) was characterized by assessment of rheological, physico-mechanical, and morphological properties.
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