Chalcogenol ligand toolbox for CdSe nanocrystals and their influence on exciton relaxation pathways.

We have employed a simple modular approach to install small chalcogenol ligands on the surface of CdSe nanocrystals. This versatile modification strategy provides access to thiol, selenol, and tellurol ligand sets via the in situ reduction of R2E2 (R=tBu, Bn, Ph; E=S, Se, Te) by diphenylphosphine (Ph2PH). The ligand exchange chemistry was analyzed by solution NMR spectroscopy, which reveals that reduction of the R2E2 precursors by Ph2PH directly yields active chalcogenol ligands that subsequently bind to the surface of the CdSe nanocrystals.

Palliative endobronchial tumor reduction by laser therapy. Procedure--immediate results--long-term results.

Over a period of 3 years, 224 laser treatments were performed on 105 patients. 84% were carried out under local anesthesia and 16% under general anesthesia. A neodymium-YAG laser (MBB-AT) was used.

[DSA of the pulmonary vessels during endobronchial laser- and afterloading therapy of malignant bronchial stenoses].

The findings are reported of the DSA examination of the pulmonary vessels in 16 patients with malignant bronchial stenoses, for whom laser or after-loading therapy was being considered. In these patients an improvement of dyspnoea can be expected only of there is adequate perfusion of the involved lung segment. DSA demonstrated stenoses or occlusions of main pulmonary or lobar arteries in six patients.

Central venous oxygen saturation for the control of automatic rate-responsive pacing.

A rate-adjusting pacemaker system is described which uses central venous oxygen saturation (SO2) for the regulation of the pacing rate. This system was tested externally in ten patients with chronically implanted VVI units. There was an average increase in cardiac output of 18% with the SO2-regulated pacemaker as compared to the situation during fixed rate stimulation.