The synthesis and characterization of a hydrochar/CeO composite along with its evaluation in methylene blue degradation under visible light are presented. The methodology consisted of a single-pass hydrothermal method, having as synthesis conditions 9 h of reaction time, 210 °C, autogenous pressure, and a biomass/CeO ratio of 100:1. The composite characterization revealed good dispersion of CeO in the carbonaceous matrix and significant synergy in the composite activation using visible irradiation.
View Article and Find Full Text PDFThis work presents a one-step synthesis methodology for preparing a hydrochar (HC) doped with TiO (HC-TiO) for its application on the degradation of crystal violet (CV) using UV and visible radiation. Byrsonima crassifolia stones were used as precursors along with TiO particles. The HC-TiO sample was synthesized at 210 °C for 9 h using autogenous pressure.
View Article and Find Full Text PDFThis study is aimed at the analysis of the pyrolysis kinetics of Nanche stone BSC ( as an agro-industrial waste using non-isothermal thermogravimetric experiments by determination of triplet kinetics; apparent activation energy, pre-exponential factor, and reaction model, as well as thermodynamic parameters to gather the required fundamental information for the design, construction, and operation of a pilot-scale reactor for the pyrolysis this lignocellulosic residue. Results indicate a biomass of low moisture and ash content and a high volatile matter content (≥70%), making BCS a potential candidate for obtaining various bioenergy products. Average apparent activation energies obtained from different methods (KAS, FWO and SK) were consistent in value (~123.
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