Toward laser-induced tuning of plasmonic response in high aspect ratio gold nanostructures.

High aspect-ratio gold nanostructures sustain Fabry-Perot-like surface plasmon responses from infrared to visible light energies. We show that some resonances can be tuned by means of laser irradiation, where low energy modes stay unperturbed. After laser irradiation, gold nanowires' tips are transformed into nanoparticles of various sizes joint to gold nanowires, producing high aspect-ratio half-dumbbells and dumbbells structures.

Intense Raman D Band without Disorder in Flattened Carbon Nanotubes.

Above a critical diameter, single- or few-walled carbon nanotubes spontaneously collapse as flattened carbon nanotubes. Raman spectra of isolated flattened and cylindrical carbon nanotubes have been recorded. The collapse provokes an intense and narrow D band, despite the absence of any lattice disorder.

Nanoscale Spatial Resolution in Far-Field Raman Imaging Using Hyperspectral Unmixing in Combination with Positivity Constrained Super-Resolution.

This work introduces hyper-resolution (HyRes), a numerical approach for spatial resolution enhancement that combines hyperspectral unmixing and super-resolution image restoration (SRIR). HyRes yields a substantial increase in spatial resolution of Raman spectroscopy while simultaneously preserving the undistorted spectral information. The resolving power of this technique is demonstrated on Raman spectroscopic data from a polymer nanowire sample.

Sub-Micron Spatial Resolution in Far-Field Raman Imaging Using Positivity-Constrained Super-Resolution.

Raman microscopy is a valuable tool for detecting physical and chemical properties of a sample material. When probing nanomaterials or nanocomposites the spatial resolution of Raman microscopy is not always adequate as it is limited by the optical diffraction limit. Numerical post-processing with super-resolution algorithms provides a means to enhance resolution and can be straightforwardly applied.

Self-ordering promoted by the nanoconfinement of poly(3-hexylthiophene) and its nanocomposite with single-walled carbon nanotubes.

Nanostructuration and self-ordering of semiconducting organic materials are required to fabricate highly efficient photovoltaic and photoemissive devices. In this work, we investigated the combined effect of melt-assisted template processing and self-ordering of high purity regio-regular poly (3-hexylthiophene) (P3HT) to obtain nanofibers of P3HT and of P3HT-single-walled carbon nanotubes (SWNT) nanocomposites. An original ordering of the polymer and the carbon nanotubes within the nanofibers, as well as their surprising anisotropic photoluminescent properties were determined by vibrational and optical spectroscopy.