Wettability of rock minerals and the underlying surface forces: A review of the implications for oil recovery and geological storage of CO.

The wettability of subsurface minerals is a critical factor influencing the pore-scale displacement of fluids in underground reservoirs. As such, it plays a key role in hydrocarbon production and greenhouse gas geo-sequestration. We present a comprehensive and critical review of the current state of knowledge on the intermolecular forces governing wettability of rock minerals most relevant to subsurface fluid storage and recovery.

Effect of ethylene oxide groups on calcite wettability reversal by nonionic surfactants: An experimental and molecular dynamics simulation investigation.

Hypothesis: Ethoxylated nonionic surfactants are promising candidates for enhanced oil recovery (EOR) from oil-wet carbonate reservoirs due to their ability to reverse the mineral wettability. The wettability-reversal efficiency increases with the number of the ethoxy (EO) groups in the surfactant molecule.

Methodology: Contact angle measurements, scanning electron microscopy (SEM) and molecular dynamics (MD) simulations were combined to investigate the wettability reversal of an oil-wet calcite by three ethoxylated nonionic surfactants with 1, 4 and 8 EO groups, respectively, to directly probe the role of the EO groups and to uncover the molecular mechanism responsible for the wettability reversal.

Quantitative Predictions and Experimental Validation of Liquid-Vapor Interfacial Tension in Binary and Ternary Mixtures of Alkanes Using Molecular Dynamics Simulations.

Liquid-vapor interfacial properties of alkane mixtures present a challenge for experimental determination, especially under conditions relevant to the energy industry processes. Molecular dynamics (MD) simulations can accurately predict interfacial tensions (IFTs) for complex alkane mixtures under virtually any conditions, thereby alleviating the need for difficult and costly experiments. MD simulations with the CHARMM force field and empirical corrections for the IFT and pressure were used to obtain the IFT for three binary mixtures of ethane (with -pentane, -hexane, and -nonane) and a ternary system (ethane/-butane/-decane) under a variety of conditions.

What is the likelihood that underage youth can obtain marijuana from licensed recreational marijuana outlets in California, a state where recreational marijuana is legal?

Objective: Since 2012, 19 states and the District of Columbia have legalized the recreational use of marijuana for adults ages 21 and older. Marijuana use at any level can impair driving performance. Prior research on enforcement of the minimum legal marijuana use age of 21 (MLMU-21) laws is limited.

Wettability reversal on oil-wet calcite surfaces: Experimental and computational investigations of the effect of the hydrophobic chain length of cationic surfactants.

Hypothesis: Oil recovery from carbonate reservoirs is often low, in a large part due to the oil-wet state of the constituent rocks. Cationic surfactants are among the most effective compounds capable of reversing the carbonate wettability to more water-wet, which significantly enhances oil recovery. Screening for the most effective cationic surfactants can be facilitated by studying the effects of specific molecular properties, such as the hydrophobic chain length, on the wettability reversal efficiency using molecular dynamics (MD) simulations.