Steering perovskite precursor solutions for multijunction photovoltaics.

Multijunction photovoltaics (PVs) are gaining prominence owing to their superior capability of achieving power conversion efficiencies (PCEs) beyond the radiative limit of single-junction cells, where improving narrow bandgap tin-lead perovskites is critical for thin-film devices. With a focus on understanding the chemistry of tin-lead perovskite precursor solutions, we herein find that Sn(II) species dominate interactions with precursors and additives and uncover the exclusive role of carboxylic acid in regulating solution colloidal properties and film crystallisation, and ammonium in improving film optoelectronic properties. Materials that combine these two function groups, amino acid salts, considerably improve the semiconducting quality and homogeneity of perovskite films, surpassing the effect of the individual functional groups when introduced as part of separate molecules.

Evaluating deuterated-xylene for use as a fusion neutron spectrometer.

The spectrum of neutrons emitted by thermonuclear plasmas encodes information about the fuel ion distribution function. Measuring these fast neutron spectra with sufficient resolution allows for the measurement of plasma properties such as the ion temperature and strength and energy of fast ion populations. Liquid organic scintillators are a commonly used fast neutron detection technology because of their high detection efficiency and ability to discriminate between neutrons and gammas.

High-precision Sm isotope analysis by thermal ionisation mass spectrometry for large meteorite samples (>1 g).

This study presents a new procedure for high-precision Sm isotope analysis by thermal ionisation mass spectrometry (TIMS) for geological samples. A four-step chemical separation scheme results in sharp separation of Sm and Nd from the same sample aliquot. The first step utilises anion exchange resin to remove Fe from the sample solution.