Metal Propionate Solutions for High-Throughput Liquid-Assisted Manufacturing of Superconducting REBaCuO (RE = Y, Gd, Sm, and Yb) Films.

The cost-effective synthesis of a series of metal propionate powders (copper, yttrium, barium, samarium, gadolinium, and ytterbium) is developed through single chemical reactions resulting in five novel crystalline forms. These complexes are valuable precursors for the preparation of epitaxial REBaCuO (REBCO) superconducting films (here, RE = Y, Sm, Gd, and Yb) through the innovative transient liquid-assisted growth (TLAG) process based on chemical solution deposition (CSD). TLAG-CSD shows impressive results with YBaCuO (YBCO), obtaining critical current densities of 2.

Chemical and Microstructural Nanoscale Homogeneity in Superconducting YBaCuO Films Derived from Metal-Propionate Fluorine-free Solutions.

Research involved in developing alternative energy sources has become a necessity to face global warming. In this context, superconductivity is an appealing solution to enhance clean electrical energy provided that lower production costs can be attained. By implementation of chemical solution deposition techniques and high-throughput growth methods, low-cost nanostructured epitaxial cuprate superconductors are timely candidates.

Kinetic Control of Ultrafast Transient Liquid Assisted Growth of Solution-Derived YBa Cu O -x Superconducting Films.

Transient liquid assisted growth (TLAG) is an ultrafast non-equilibrium growth process mainly governed by kinetic parameters, which are only accessible through fast in situ characterizations. In situ synchrotron X-ray diffraction (XRD) analysis and in situ electrical resistivity measurements are used to derive kinetic diagrams of YBa Cu O (YBCO) superconducting films prepared via TLAG and to reveal the unique peculiarities of the process. In particular, diagrams for the phase evolution and the YBCO growth rates have been built for the two TLAG routes.

Nonlinear complexification of periodic orbits in the generalized Landau scenario.

We have found a way for penetrating the space of the dynamical systems toward systems of arbitrary dimension exhibiting the nonlinear mixing of a large number of oscillation modes through which extraordinarily complex time evolutions may arise. The system design is based on assuring the occurrence of a number of Hopf bifurcations in a set of fixed points of a relatively generic system of ordinary differential equations, in which the main peculiarity is that the nonlinearities appear through functions of a linear combination of the system variables. The paper outlines the design procedure and presents a selection of numerical simulations with a variety of designed systems whose dynamical behaviors are really rich and full of unknown features.

Ultrafast transient liquid assisted growth of high current density superconducting films.

The achievement of high growth rates in YBaCuO epitaxial high-temperature superconducting films has become strategic to enable high-throughput manufacturing of long length coated conductors for energy and large magnet applications. We report on a transient liquid assisted growth process capable of achieving ultrafast growth rates (100 nm s) and high critical current densities (5 MA cm at 77 K). This is based on the kinetic preference of Ba-Cu-O to form transient liquids prior to crystalline thermodynamic equilibrium phases, and as such is a non-equilibrium approach.