Unlocking New Frontiers: Photo-Isomerism and Magnetic Properties in Multifunctional Hetero-Tetra-Metallic Complexes.

Hetero-tetra-metallic complexes, FeCuLnCo (Ln=Gd, Tb, Dy), combining magnetic properties and photo-isomerism, were obtained through the rational assembly of the photo-switching nitroprusside anion Fe with new magnetic Schiff base CuLnCo precursors. Herein, we describe the synthesis and characterisation of these compounds followed by a demonstration of their multifunctional character. Particularly noteworthy is the FeCuTbCo complex which is one of the few examples of a photo-isomerisable SMM.

Synthesis and Biological Evaluation of a New Biphenyl-Based Organogold(III) Complex with In Vitro and In Vivo Anticancer Activity.

Despite recent advances in cancer treatment, there is still a need for novel compounds with antineoplastic activity. Among 11 biphenyl-based organogold(III) -heterocyclic carbene (NHC) (BGC) complexes of general formula [(C^C)Au(NHC-pyr)X], where (C^C) = 4,4'-ditertbutylbiphenyl, X = Cl or phenylacetylide, and (NHC-pyr) is a pyridyl-substituted NHC ligand, the complex bearing a 4-CF-pyridyl substituent and a chloride ligand showed promising antineoplastic activity on the triple negative breast cancer cell line. was able to induce cell apoptosis but had no effect on the cell cycle.

Visual Snow Syndrome is unstable: A longitudinal investigation of VSS symptoms in a Naïve population.

Objective: This study aimed to investigate the nature of subclinical Visual Snow Syndrome (VSS). We sought to develop a means of recruiting naïve participants with subclinical VSS symptoms to participate in research; and to understand whether subclinical VSS symptoms are stable across time. VSS is a recently characterised neurological condition, whose primary symptom is visual snow (dynamic noise in the visual field).

Post-metallation functionalization of the [(C^C)Au(P^P)] scaffold through a hydrothiolation reaction.

Complex 1 [(C^C)Au(dppv)]PF (dppv = -1,2-diphenylphosphinoethylene) is reported to react efficiently and selectively with aliphatic and aromatic thiols in the presence of a base. This methodology enables the smooth introduction of various functional groups on the [(C^C)Au(P^P)] scaffold.