Glassy states in adsorbing surfactant-microgel soft nanocomposites.

Mixtures of polymer-colloid hybrids such as star polymers and microgels with non-adsorbing polymeric additives have received a lot of attention. In these materials, the interplay between entropic forces and softness is responsible for a wealth of phenomena. By contrast, binary mixtures where one component can adsorb onto the other one have been far less studied.

Versatile Encapsulation Technology Based on Tailored pH-Responsive Amphiphilic Polymers: Emulsion Gels and Capsules.

We present a multipurpose technology to encapsulate hydrophobic substances in micron-sized emulsion droplets and capsules. The encapsulating agent is a comblike stimuli-responsive copolymer comprising side-chain surfactants attached to a methacrylic acid/ethyl acrylate polyelectrolyte backbone. The composition and structure of the hydrophobic moieties of the side chains are customized to tune the particle morphology and the processing conditions.