Publications by authors named "J A Navio"

Barium phosphate (Ba(PO)) is a class of material that has attracted significant attention thanks to its chemical stability and versatility. However, the use of Ba(PO) as a photocatalyst is scarcely reported, and its use as a photocatalyst has yet to be reported. Herein, Ba(PO) nanoflakes synthesis is optimized using sol-gel and hydrothermal methods.

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AgBr/NaTaO composites, with different molar % of NaTaO (Br/NTO(X%)), have been synthesized by simple precipitation methods; bare NaTaO was synthesized by hydrothermal procedure, while AgBr was synthesized by a precipitation procedure using cetyl-tri-methyl-ammonium bromide (CTAB) and AgNO. Samples have been characterized by X-ray diffraction (XRD), N adsorption, UV-vis diffuse reflectance spectroscopy (DRS), Fourier-transform infrared spectroscopy (FT-IR), Transmission electron microscopy (TEM) and X-ray photoelectron spectroscopy (XPS). Photocatalytic activity of the as-prepared photo-catalysts was evaluated through photocatalytic degradation of rhodamine B (RhB), methyl orange (MO) and caffeic acid (CAFA) under UV and visible illumination.

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In this work, the core-shell PANI@WO composite was obtained from the reaction of aniline monomer polymerization with WO particles; sodium persulfate was used as an oxidant. Various analytical techniques such as scanning electron microscopy (SEM-EDS), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), Brunauer-Emmett-Teller (BET), and X-ray photoelectron spectroscopy (XPS) were used to characterize the as-prepared PANI@WO adsorbent, which well confirmed that the WO particles were coated by polyaniline polymer. The PANI@WO composite was tested as an adsorbent to remove reactive orange G (OG) for the first time.

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A WO@PANI heterojunction photocatalyst with a various mass ratio of polyaniline to WO was obtained via the in situ oxidative deposition polymerization of aniline monomer in the presence of WO powder. The characterization of WO@PANI composites was carried via X-ray diffraction (XRD), scanning electron microscopy (SEM-EDS), transmission electron microscopy (TEM), Fourier transform infrared spectroscopy (FT-IR), ultraviolet-visible diffuse reflection spectroscopy (DRS), X-ray photoelectron spectroscopy (XPS) and photoluminescence spectroscopy (PL). The photocatalytic efficiency of WO@PANI photocatalysts was assessed by following the decomposition of the Rhodamine B (RhB) dye under visible light irradiation (λ >420 nm).

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Two series of new photocatalysts were synthesized based on modification with Pd of the commercial P25 photocatalyst (EVONIK). Two techniques were employed to incorporate Pd nanoparticles on the P25 surface: photodeposition (series Pd-P) and impregnation (series Pd-I). Both series were characterized in depth using a variety of instrumental techniques: BET, DRS, XRD, XPS, TEM, FTIR and FESEM.

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