Publications by authors named "Ismail Jusoh"
Chlorido{4-cyclo-hexyl-1-[1-(pyridin-2-yl-κN)ethyl-idene]thio-semicarbazidato-κ(2)N(1),S}diphenyl-tin(IV).
Acta Crystallogr Sect E Struct Rep Online
April 2012
The distorted octa-hedral geometry about the Sn(IV) atom in the title compound, [Sn(C(6)H(5))(2)(C(14)H(19)N(4)S)Cl], is defined by the N,N,S-tridentate Schiff base ligand, two mutually trans ipso-C atoms of the Sn-bound phenyl groups, and the Cl atom which is trans to the azo N atom. The two five-membered chelate rings and pyridyl ring are almost coplanar with the dihedral angle between the outer five-membered chelate and pyridine rings being 5.39 (8)°.
View Article and Find Full Text PDFAqua-chlorido{2-[2-(cyclo-hexyl-carbamo-thioyl-κS)hydrazinyl-idene-κN]propano-ato(2-)}phenyl-tin(IV).
Acta Crystallogr Sect E Struct Rep Online
August 2010
Article Synopsis
- The organotin compound features a tin (Sn) atom that is bonded to various atoms including sulfur (S), oxygen (O), and nitrogen (N) from a tridentate ligand, as well as a chloride ligand, phenyl carbon, and a water molecule, creating a distorted octahedral shape.
- Coordinated water molecules facilitate connections between organotin molecules through O-H⋯O hydrogen bonds with carbonyl and carboxylate groups, forming 12-membered synthons.
- These synthons combine to create supramolecular chains that align along the c axis, with additional stacking in the ac plane and interlayer connections via N-H⋯Cl hydrogen bonds.