Biodegradable Poly(Butylene Succinate) Nanocomposites Based on Dimeric Surfactant Organomodified Clays with Enhanced Water Vapor Barrier and Mechanical Properties.

Biocomposites based on biodegradable polybutylene succinate (PBS) and organomodified clays (OMt) were prepared by melt blending process. The OMt nanofillers were obtained by ion exchange reaction between sodium montmorillonite (Mt) and gemini surfactants bearing 4-decyloxyphenylacetamide hydrophobic chains and ethylene or hexylene spacer. X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), and rheological measurement results showed that the investigated hybrids present a uniform dispersion with an exfoliation of clay into the PBS matrix, particularly for short spacer surfactant based composites.

Polylactic acid/Gemini surfactant modified clay bio-nanocomposites: Morphological, thermal, mechanical and barrier properties.

To improve PLA's properties and overcome its drawbacks such us poor thermal stability, resistance and gas barrier properties, several studies have been performed using different nanofillers. In this work, PLA nanocomposites reinforced by three organoclays, OMt(8-4-8), OMt(10-4-10) and OMt(12-4-12) at various weight percentages (1 and 3 wt%) were prepared by melt mixing using a twin-screw extruder. The organoclays were obtained from sodium montmorillionite and gemini surfactants bearing different hydrophobic chain lengths.