Synergistic electrochemical performance of textile sludge based activated carbon with reduced graphene oxide as electrode for supercapacitor application.

The procedure for disposing of textile waste sludge requires sustainable solutions due to numerous environmental issues associated with its disposal. The majority of textile manufacturers incinerate the waste sludge to meet their heating demands, which is harmful to the environment. It can also be used in soil amendment, biodegradable products, construction material and water treatment process as absorbent to remove the heavy metals etc.

Photocatalytic Dye Degradation from Textile Wastewater: A Review.

The elimination of dyes discharged from industrial wastewater into water bodies is crucial due to its detrimental effects on aquatic organisms and potential carcinogenic impact on human health. Various methods are employed for dye removal, but they often fall short in completely degrading the dyes and generating large amounts of suspended solids. Hence, there is a critical need for an efficient process that can achieve complete dye degradation with minimal waste emission.

Fabrication of MoS/rGO hybrids as electrocatalyst for water splitting applications.

Environmental degradation and energy constraint are important risks to long-term sustainability in the modern world. Water splitting is a vital approach for environmentally friendly and sustainable energy storage, providing a clean way to produce hydrogen without pollutants. Preparing a catalyst that is active, bifunctional, and durable for water splitting is a difficult task.

Efficient sorption of As(III) from water by magnetite decorated porous carbon extracted from a biowaste material.

Arsenic is a highly toxic metal that causes cancer even at a low concentration and its removal from water resources is challenging. Herein, carbon extracted from waste onion bulbs is activated to cater for porosity and functionalized with magnetite (FeO) nanoparticles (named MCK6) to address the challenge of As(III) removal. Synthesized MCK6 was highly mesoporous having a surface area of 208 m/g, where magnetite nanoparticles (≤ 10 nm) are homogeneously distributed within a porous network.

Catalyzing Sustainable Water Splitting with Single Atom Catalysts: Recent Advances.

Electrochemical water splitting for sustainable hydrogen and oxygen production have shown enormous potentials. However, this method needs low-cost and highly active catalysts. Traditional nano catalysts, while effective, have limits since their active sites are mostly restricted to the surface and edges, leaving interior surfaces unexposed in redox reactions.

A zeolitic imidazolate framework (ZIF-67) and graphitic carbon nitride (g-CN) composite based efficient electrocatalyst for overall water-splitting reaction.

Designing of non-noble, cost-effective, sustainable catalysts for water splitting is essential for hydrogen production. In this research work, ZIF-67, g-CN, and their composite (1, 3, 5, 6, 8 wt% g-CN@ZIF-67) are synthesized, and various techniques, XRD, FTIR, SEM, EDX and BET are used to examine their morphological properties for electrochemical water-splitting. The linkage of ZIF-67 with g-CN synergistically improves the electrochemical kinetics.

Optimization of bandgap reduction in 2-dimensional GO nanosheets and nanocomposites of GO/iron-oxide for electronic device applications.

In this report we have developed different fabrication parameters to tailor the optical bandgap of graphene oxide (GO) nanosheets to make it operational candidate in electronic industry. Here we performed two ways to reduce the bandgap of GO nanosheets. First, we have optimized the oxidation level of GO by reducing amount of oxidizing agent (i.

Effect of Pyrolysis on iron-metal organic frameworks (MOFs) to FeC @ FeC for diesel production in Fischer-Tropsch Synthesis.

The Fischer-Tropsch Synthesis (FTS) is a significant catalytic chemical reaction that produces ultra-clean fuels or chemicals with added value from a syngas mixture of CO and H obtained from biomass, coal, or natural gas. The presence of sulfur is not considered good for producing liquid fuels for(FTS). In this study, we reveal that the presence of sulfur in ferric sulfate Fe(SO) MOF provides the high amount, 52.

A review on development of metal-organic framework-derived bifunctional electrocatalysts for oxygen electrodes in metal-air batteries.

Worldwide demand for oil, coal, and natural gas has increased recently because of odd weather patterns and economies recovering from the pandemic. By using these fuels at an astonishing rate, their reserves are running low with each passing decade. Increased reliance on these sources is contributing significantly to both global warming and power shortage problems.

Metal-organic framework derived vanadium oxide supported nanoporous carbon structure as a bifunctional electrocatalyst for potential application in metal air batteries.

High-efficiency, sustainable, non-precious metal-based electrocatalysts with bifunctional catalytic activity for the oxygen reduction reaction (ORR) and the oxygen evolution reaction (OER) are essential for metal-air batteries. In this research, a bifunctional electrocatalyst is developed by synthesizing a novel nanoporous vanadium oxide/carbon composite (NVC-900) through pyrolysis of a highly efficient vanadium metal-organic framework, MIL-101 (V). The fabrication process was conveniently carried out by pyrolyzing the synthesized MIL-101 (V) at 900 °C, producing vanadium oxide nanoparticles embedded in the extensively distributed pores of the carbon network.

Fabrication of cellulose paper-based counter electrodes for flexible dye-sensitized solar cells.

Here, we introduce the synthesis and deposition of organic/inorganic composite ink on cellulose paper using a rapid ultrasonic spray deposition approach that can be incorporated as a counter electrode (CE) in flexible dye-sensitized solar cells (FDSSCs). The composite ink comprised a copper indium sulfide (CuInS) nanostructure ink and dispersion of poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate) (PEDOT:PSS) in water. Fabricated counter electrodes are biodegradable, environment-friendly, flexible, and economical and meet the requirements for sustainable green energy.

Conversion of Plastic Waste to Carbon-Based Compounds and Application in Energy Storage Devices.

At present, plastic waste accumulation has been observed as one of the most alarming environmental challenges, affecting all forms of life, economy, and natural ecosystems, worldwide. The overproduction of plastic materials is mainly due to human population explosion as well as extraordinary proliferation in the global economy accompanied by global productivity. Under this threat, the development of benign and green alternative solutions instead of traditional disposal methods such as conversion of plastic waste materials into cherished carbonaceous nanomaterials such as carbon nanotubes (CNTs), carbon quantum dots (CQDs), graphene, activated carbon, and porous carbon is of utmost importance.

A TiO composite with graphitic carbon nitride as a photocatalyst for biodiesel production from waste cooking oil.

Semiconductor-based photocatalysts have attracted a lot of interest due to their environmental friendliness and high stability. Waste cooking oil can be converted to biodiesel by the process of transesterification. A TiO/g-CN combination was prepared by using a wet impregnation process.

Recent advances in the metal-organic framework-based electrocatalysts for the hydrogen evolution reaction in water splitting: a review.

Water splitting is an important technology for alternative and sustainable energy storage, and a way for the production of hydrogen without generating pollution. In recent years, metal-organic frameworks (MOFs) have become the most capable multifunctional resources because of their high surface areas, tunable porosity, simple modification of compositions, and potential for use as precursors with a variety of morphological structures. Based on these qualities, many MOFs and their derived materials are utilized as electrocatalysts for the water splitting reaction.

Metal-organic framework based electrode materials for lithium-ion batteries: a review.

Metal-organic frameworks (MOFs) with efficient surface and structural properties have risen as a distinctive class of porous materials through the last few decades, which has enabled MOFs to gain attention in a wide range of applications like drug delivery, gas separation and storage, catalysis and sensors. Likewise, they have also emerged as efficient active materials in energy storage devices owing to their remarkable conducting properties. Metal-organic frameworks (MOFs) have garnered great interest in high-energy-density rechargeable batteries and super-capacitors.

A comprehensive and critical review of the recent progress in electrocatalysts for the ethanol oxidation reaction.

The human craving for energy is continually mounting and becoming progressively difficult to gratify. At present, the world's massive energy demands are chiefly encountered by nonrenewable and benign fossil fuels. However, the development of dynamic energy cradles for a gradually thriving world to lessen fossil fuel reserve depletion and environmental concerns is currently a persistent issue for society.

The Development of Highly Fluorescent Hemicyanine and Dicyanoisophorone Dyes for Applications in Dye-Sensitized Solar Cells.

Ruthenium-based metal complex dyes have been employed extensively in dye-sensitized solar cells (DSSCs) as photosensitizers, but the cost and toxicity of metal complexes have promoted the development of metal-free organic dyes. The present investigation deals with the synthesis of hemicyanine and Dicyanoisophorone (DCI) based dyes adopting the D-π-A strategy, and their application on sensitization of nano-crystalline ZnO electrodes by appending the carboxyl (COOH) anchoring group as a pendant on the primary skeleton of dyes. Dyes have been characterized by UV, FTIR, and NMR spectroscopic studies.

Advanced Strategies in Metal-Organic Frameworks for CO Capture and Separation.

The continuous carbon dioxide (CO ) gas emissions associated with fossil fuel production, valorization, and utilization are serious challenges to the global environment. Therefore, several developments of CO capture, separation, transportation, storage, and valorization have been explored. Consequently, we documented a comprehensive review of the most advanced strategies adopted in metal-organic frameworks (MOFs) for CO capture and separation.

Electrochemical Reduction of CO: A Review of Cobalt Based Catalysts for Carbon Dioxide Conversion to Fuels.

Electrochemical CO reduction reaction (CORR) provides a promising approach to curbing harmful emissions contributing to global warming. However, several challenges hinder the commercialization of this technology, including high overpotentials, electrode instability, and low Faradic efficiencies of desirable products. Several materials have been developed to overcome these challenges.

Electrocatalytic study of NiO-MOF with activated carbon composites for methanol oxidation reaction.

In this work, the methanol oxidation reaction is investigated on Ni based metal organic frameworks (MOF) and its composites with biomass derived activated carbon. NiO-MOF and composites with activated carbon were synthesized using hydrothermal method. SEM, EDX, and XRD, FTIR, TGA techniques were used for characterization of composites.

Metal Organic Frameworks Derived Sustainable Polyvinyl Alcohol/Starch Nanocomposite Films as Robust Materials for Packaging Applications.

Bio-nanocomposites-based packaging materials have gained significance due to their prospective application in rising areas of packaged food. This research aims to fabricate biodegradable packaging films based upon polyvinyl alcohol (PVA) and starch integrated with metal-organic frameworks (MOFs) or organic additives. MOFs offer unique features in terms of surface area, mechanical strength, and chemical stability, which make them favourable for supporting materials used in fabricating polymer-based packaging materials.

Designing and theoretical study of fluorinated small molecule donor materials for organic solar cells.

A recently synthesized photoactive donor named fluorinated thienyl-substituted benzodithiophene (DRTB-FT), modified with four novel end capped acceptor molecules, has been investigated through different electrical, quantum, and spectrochemical techniques for its enhanced electro-optical and photovoltaic properties. DRTB-FT was connected to 2-methylenemalononitrile (D-1), 2-methylene-3-oxobutanenitrile (D-2), 2-(2-methylene-3-oxo-2,3-dihydro-1H-inden-1-ylidene) malononitrile (D-3), and 3-methyl-5methylene-2-thioxothiazolidin-4-one (D-4) as terminal acceptor moieties. The architectural D-1 and D-3 molecules owe reduced optical band gap of 2.

Zeolitic imidazolate framework (ZIF)-derived porous carbon materials for supercapacitors: an overview.

The present analysis focuses on the synthetic methods used for the application of supercapacitors with various mysterious architectures derived from zeolitic imidazolate frameworks (ZIFs). ZIFs represent an emerging and unique class of metal-organic frameworks with structures similar to conventional aluminosilicate zeolites, consisting of imidazolate linkers and metal ions. Their intrinsic porous properties, robust functionalities, and excellent thermal and chemical stabilities have resulted in a wide range of potential applications for various ZIF materials.

Investigating the potential of locally sourced wastewater as a feedstock of microbial desalination cell (MDC) for bioenergy production.

Freshwater sources are limited and access to clean water is an acute challenge in recent decades. The sustainable water treatments methods are need of time and water desalination is one of the most interesting technology. Most desalination technologies are required high energy input while Microbial Desalination Cells (MDCs) represent a sustainable option that has added benefit of solving the ever-increasing wastewater treatment and management problem.