The Influence of Alkyl Spacers and Molecular Weight on the Charge Transport and Storage Properties of Oxy-Bithiophene-Based Conjugated Polymers.

Conjugated polymers (CPs) with polar side chains can conduct electronic and ionic charges simultaneously, making them promising for bioelectronics, electrocatalysis and energy storage. Recent work showed that adding alkyl spacers between CP backbones and polar side chains improved electronic charge carrier mobility, reduced swelling and enhanced stability, without compromising ion transport. However, how alkyl spacers impact polymer backbone conformation and, subsequently, electronic properties remain unclear.

Ion Size-Dependent Electrochromism in Air-Stable Napthalenediimide-Based Conjugated Polymers.

Conjugated polymers (CPs) that show stable and reversible cation insertion/deinsertion under ambient conditions hold great potential for optoelectronic and energy storage devices. However, n-doped CPs are prone to parasitic reactions upon exposure to moisture or oxygen. This study reports a new family of napthalenediimide (NDI) based conjugated polymers capable of undergoing electrochemical n-type doping in ambient air.