Direct Ag-Hg amalgamation in the nanoscale on the surface of biosourced amorphous silica.

Mercury poses a significant threat to air, soil, and water ecosystems. Mercury-based alloys, aka amalgams, are already known for their effectiveness in mercury capture in water and gaseous streams. However, limited research has been published on direct amalgamation, the process involving a direct redox reaction between two metals, occurring on the surface of amorphous silica.

Micro plastics mapping in the agricultural sector of Cyprus.

The impact of Microplastic Pollution (MPs) on human health, the environment, economy, and society has been previously investigated. However, there is a lack of comprehensive understanding regarding specific areas that require urgent measures to address marine pollution. The accumulation of MPs in Mediterranean coastal environments is particularly noteworthy.

Adsorptive removal of anthracene from water by biochar derived amphiphilic carbon dots decorated with chitosan.

Anthracene belongs to the polycyclic aromatic hydrocarbon (PAH) consisting of benzene rings, unusually highly stable through more π-electrons and localized π-bond in entire rings. Aqueous-phase anthracene adsorption using carbon-based materials such as biochar is ineffective. In this paper, carbon dots (CDs) derived from the acid treatment of coconut shell biochar (CDs/MCSB) decorated with chitosan (CS) are successfully synthesized and applied for anthracene removal from aqueous solutions.

Iodide Removal by Resorcinol-Formaldehyde Carbon Aerogels.

The adsorption technique is widely used in water purification, and its efficiency can be significantly improved by target-specific adsorbent design. Research on iodine and its ion removal from water has attracted a great deal of interest due to increased concentrations in the environment and acute toxic effects, e.g.

Green-Synthesized Silver Nanoparticle-Assisted Radiofrequency Ablation for Improved Thermal Treatment Distribution.

Thermal ablation therapy is known as an advantageous alternative to surgery allowing the treatment of multiple tumors located in hard-to-reach locations or treating patients with medical conditions that are not compatible with surgery. Appropriate heat propagation and precise control over the heat propagation is considered a weak point of thermal ablation therapy. In this work, silver nanoparticles (AgNPs) are used to improve the heat propagation properties during the thermal ablation procedure.

Synthetic Amphoteric Cryogels as an Antidote against Acute Heavy Metal Poisoning.

The effectiveness of an amphoteric cryogel (AAC) as an oral sorbent (enerosorbent) for the treatment of acute poisoning of small animals (rats) with heavy metals (HMs) was studied in in vivo experiments. The morphological structure of the cryogel was examined using scanning electron microscopy/energy-dispersive X-ray analysis and confocal microscopy. The use of the cryogel in the treatment of rats administered an LD dose of Cd(NO), CsNO, Sr(NO), or HgCl in aqueous solution showed their high survival rate compared to the control group, which did not receive such treatment.

Anaerobic Membrane Bioreactors for Municipal Wastewater Treatment: A Literature Review.

Currently, there is growing scientific interest in the development of more economic, efficient and environmentally friendly municipal wastewater treatment technologies. Laboratory and pilot-scale surveys have revealed that the anaerobic membrane bioreactor (AnMBR) is a promising alternative for municipal wastewater treatment. Anaerobic membrane bioreactor technology combines the advantages of anaerobic processes and membrane technology.

Distributed Sensing Network Enabled by High-Scattering MgO-Doped Optical Fibers for 3D Temperature Monitoring of Thermal Ablation in Liver Phantom.

Thermal ablation is achieved by delivering heat directly to tissue through a minimally invasive applicator. The therapy requires a temperature control between 50-100 °C since the mortality of the tumor is directly connected with the thermal dosimetry. Existing temperature monitoring techniques have limitations such as single-point monitoring, require costly equipment, and expose patients to X-ray radiation.

Mercury (Hg) Contaminated Sites in Kazakhstan: Review of Current Cases and Site Remediation Responses.

Mercury (Hg) emissions from anthropogenic sources pose a global problem. In Central Asia, Kazakhstan's central and northern regions are among the most severely Hg-contaminated territories. This is due to two former acetaldehyde (in Temirtau) and chlor-alkali (in Pavlodar) plants, discharges from which during the second half of the 20th century were estimated over 2000 tons of elemental Hg.

Removal of Cd from Water by Use of Super-Macroporous Cryogels and Comparison to Commercial Adsorbents.

In this study amphoteric cryogels were synthesized by the use of free-radical co-polymerization of acrylate-based precursors (methacrylic acid and 2-acrylamido-2-methyl-1-propansulfonic acid) with allylamine at different ratios. The physico-chemical characteristics of the cryogels were examined using SEM/EDX, FT-IR, XPS and zeta potential measurements. The cryogels were tested toward Cd removal from aqueous solutions at various pH and initial concentrations.

Effective photochemical treatment of a municipal solid waste landfill leachate.

This work aimed at studying the photochemical treatment of a landfill leachate using ultraviolet light, hydrogen peroxide, and ferrous or ferric ions, in a batch recycle photoreactor. The effect of inorganic carbon presence, pH, initial H2O2 amount (0-9990 mg L-1) as well as Fe(II) (200-600 ppm) and Fe(III) (300-700 ppm) concentrations on the total carbon removal and color change was studied. Prior to the photochemical treatment, a pretreatment process was applied; inorganic nitrogen and inorganic carbon were removed by means of air stripping and initial pH regulation, respectively.

Measuring the level of environmental performance in insular areas, through key performed indicators, in the framework of waste strategy development.

To measure "something that is not there", is not easy and at the same time not fully understandable and perceived by the citizens. Several elements (such as, waste production, waste management cost, social attitude and behaviour, etc.) interrupt and disturb any strategy in the framework of waste management.

Distributed 2D temperature sensing during nanoparticles assisted laser ablation by means of high-scattering fiber sensors.

The high demand in effective and minimally invasive cancer treatments, namely thermal ablation, leads to the demand for real-time multi-dimensional thermometry to evaluate the treatment effectiveness, which can be also assisted by the use of nanoparticles. We report the results of 20-nm gold and magnetic iron oxide nanoparticles-assisted laser ablation on a porcine liver phantom. The experimental set-up consisting of high-scattering nanoparticle-doped fibers was operated by means of a scattering-level multiplexing arrangement and interrogated via optical backscattered reflectometry, together with a solid-state laser diode operating at 980 nm.

Surface Interactions and Mechanisms Study on the Removal of Iodide from Water by Use of Natural Zeolite-Based Silver Nanocomposites.

In this work a natural zeolite was modified with silver following two different methods to derive AgO and Ag nanocomposites. The materials were fully characterized and the results showed that both materials were decorated with nanoparticles of size of 5-25 nm. The natural and modified zeolites were used for the removal of iodide from aqueous solutions of initial concentration of 30-1400 ppm.

Efficient removal of mercury (II) from water by use of cryogels and comparison to commercial adsorbents under environmentally relevant conditions.

Mercury is a toxic element, which can be found in air, water and soil in several inorganic and organic forms. Mercury pollution comes from a variety of industrial sources, including vinyl-chloride, pulp and paper, fertilizers and pharmaceuticals industry, gold mining and cement production. Gels have increasingly attracted the interest over the past decades and one of the investigated applications is the fast removal of organic substances, metals and other cations and anions from water.

Behaviour of Aquaporin Forward Osmosis Flat Sheet Membranes during the Concentration of Calcium-Containing Liquids.

This study aims to examine the scaling and performance of flat sheet aquaporin FO membranes in the presence of calcium salts. Experiments showed that the application of calcium sulphate (CaSO) resulted in an 8%-78% decline in the water flux. An increase in the cross-flow velocity from 3 to 12 cm/s reduced the decline in the flux by 16%.

Detailed municipal solid waste composition analysis for Nur-Sultan City, Kazakhstan with implications for sustainable waste management in Central Asia.

A detailed characterization of municipal solid waste (MSW) beyond a standard compositional analysis may offer insights useful for improving waste management systems. The present paper contributes to the scarce literature in the field by presenting new data from a rapidly developing Central Asian city, the capital of Kazakhstan, Nur-Sultan. Three sampling campaigns (each 1 week long) have been conducted at the city landfill over a 1-year period (2018-2019), and a detailed characterization for selected waste components and sub-components has been performed.

Sustainable metropolitan areas perspectives through assessment of the existing waste management strategies.

Human activities are considered among the main producers of any kind of pollution. This paper, through a Driver-Pressure-State-Impact-Response (DPSIR) model analyses, focuses on the evaluation and assessment of the existing practices, procedures, and results obtained in order to determine whether the municipal solid waste (MSW) management implemented in three major Greek municipalities in the greater urban area of Attica, namely the municipalities of Nea Smirni, Vyronas, and Piraeus, could be considered viable and sustainable. The evaluation indicated that MSW in Greek cities have reduced over the last years, also suggesting a steady downward trend, which could be considered consistent with that of the per capita incomes in Greece due to the extended economic austerity, while at the same time the recycling indicator seems to optimize.

A review of cryogels synthesis, characterization and applications on the removal of heavy metals from aqueous solutions.

The physical and chemical attributes of cryogels, such as the macroporosity, elasticity, water permeability and ease of chemical modification have attracted strong research interest in a variety of areas, such as water purification, catalysis, regenerative medicine, biotechnology, bioremediation and biosensors. Cryogels have shown high removal efficiency and selectivity for heavy metals, nutrients, and toxic dyes from aqueous solutions but there are challenges when scaling up from lab to commercial scale applications. This paper represents an overview of the most recent advances in the use of cryogels for the removal of heavy metals from water and attempts to fill the gap in the literature by deepening the understanding on the mechanisms involved, which strongly depend on the initial monomer composition and post-modification agent precursors used in synthesis.

Degradation and mineralization of 4-tert-butylphenol in water using Fe-doped TiO catalysts.

In the present work, the photocatalytic degradation and mineralization of 4-tert-butylphenol in water was studied using Fe-doped TiO nanoparticles under UV light irradiation. Fe-doped TiO catalysts (0.5, 1, 2 and 4 wt.

Seasonal characterisation of municipal solid waste from Astana city, Kazakhstan: Composition and thermal properties of combustible fraction.

This study presents the results of a seasonal municipal solid waste composition campaign, that took place over the period of September 2017 to June 2018 in the capital city of Kazakhstan, Astana. Four sampling campaigns were conducted in order to identify the seasonal variation of municipal solid waste composition, recyclables and energy potential materials, such as combustible fraction, useful for the evaluation of waste-to-energy potential. The combustible fraction was analysed for thermal fuel properties, such as proximate and elemental analyses and gross calorific value.

Application of Nanoparticles and Nanomaterials in Thermal Ablation Therapy of Cancer.

Cancer is one of the major health issues with increasing incidence worldwide. In spite of the existing conventional cancer treatment techniques, the cases of cancer diagnosis and death rates are rising year by year. Thus, new approaches are required to advance the traditional ways of cancer therapy.

Experimental study of zeolitic diffusion by use of a concentration-dependent surface diffusion model.

Surface diffusivity in adsorption and ion exchange processes is probably the most important property studied expensively in the literature but some aspects, especially its dependence on solid phase concentration, is still an open subject to discussion. In this study a new concentration-dependent surface diffusion model, equipped with a flexible double selectivity equilibrium relationship is applied on the removal of Pb, Cr, Fe and Cu from aqueous solutions using a natural zeolite. The model incorporates the Chen-Yang surface diffusivity correlation able to deal with positive and negative dependence with surface coverage.

Removal of iodide from water using silver nanoparticles-impregnated synthetic zeolites.

Synthetic zeolite-based Ag-nanocomposites were synthesized, characterized and used to remove iodide from aqueous solutions. The results showed high removal efficiency (up to 94.85%) and the formation silver iodide which is stable into the material.