Epigenetically modified nucleobases (5hmc, 5fc, and 5caC) interaction with boron and nitrogen doped porous graphene (B/N-pGr) as promising materials for biosensing application: A density functional theory calculations.

In this present work, porous graphene (pGr), boron (B-pGr), and nitrogen (N-pGr) doped porous sheets are explored as a bio-sensor device for sensing modified nucleobases (MBs) in cancer therapy using density functional theory (DFT). The obtained geometrical, energetic and electronic properties revealed that the B-pGr is highly reactive and it adsorbs MBs better than the pGr and N-pGr, because B atom holds empty p-orbitals which easily interact with partially filled p-orbital of N and O atom. Thus, the adsorption energies of 5hmc, 5caC, and 5fc on B-pGr are high rather than the pGr and N-pGr.

Visible light driven reduced graphene oxide supported ZnMgAl LTH/ZnO/g-CN nanohybrid photocatalyst with notable two-dimension formation for enhanced photocatalytic activity towards organic dye degradation.

In this study, 2D/2D/2D heterostructured r-GO/LTH/ZnO/g-CN nanohybrid were synthesized through hydrothermal method. The strong electrostatic interaction between the negatively charged g-CN and r-GO nanosheets with positively charged layered triple hydroxide (LTH) nanosheets are effectively influences the successful formation of heterojunction. The LTH nanosheets are well spread on the g-CN nanosheets combined with r-GO.