The removal of nitrogen from coal tar pitch (CTP) through the hydrodenitrogenation (HDN) of CTP and its molecular behavior were evaluated in the presence of NiMo/γ-alumina and CoMo/γ-alumina catalysts. Fourier transform ion cyclotron resonance mass spectrometry with atmospheric pressure photoionization was used to analyze the complicated chemical classes and species of CTP and the treated products at the molecular level. Nitrogen species were qualitatively analyzed before and after hydrotreatment.
View Article and Find Full Text PDFUnlabelled: We successfully prepared activated carbon derived from polyethylene terephthalate (PET) via carbonization and subsequent activation under various conditions and applied it as active material for supercapacitors. In the activation, we used CO for physical activation or KOH for chemical activation and varied the activation temperature from 600 °C to 1,000 °C. We found that CO activation is unsuitable because of insufficient pore formation or low activation yield.
View Article and Find Full Text PDFHigh-performance supercapacitors based on activated carbons (AC) derived from polyethylene (PE), which is one of the most abundant plastic materials worldwide, are fabricated. First, PE carbons (PEC) are prepared via sulfonation, which is a reported solution for successful carbonization of innately non-carbonizable PE. Then, the physico-electrical changes of PECs upon a chemical activation process are explored.
View Article and Find Full Text PDFMacromol Rapid Commun
January 2022
Even though plastic improved the human standard of living, handling the plastic waste represents an enormous challenge. It takes more than 100 years to decompose discarded or buried waste plastics. Microplastics are one of the causes of significantly pervasive environmental pollutants.
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