In the context of experimental optics- and photonics-research, motorized, high-precision rotation stages are an integral part of almost every laboratory setup. Nevertheless, their availability in the laboratory is limited due to the relatively high acquisition costs in the range of several 1000€ and is often supplemented by manual rotation stages. If only a single sample is to be analyzed repeatedly at two different angles or the polarization of a laser source is to be rotated, this approach is understandable.
View Article and Find Full Text PDFPolarons play a major role in the description of optical, electrical and dielectrical properties of several ferroelectric oxides. The motion of those particles occurs by elementary hops among the material lattice sites. In order to compute macroscopic transport parameters such as charge mobility, normal (i.
View Article and Find Full Text PDFStranded seals are often infected with a broad range of parasites, although whether they are the cause of significant morbidity or an incidental finding is usually unclear. In this study we used stable isotope ratio analysis, a method frequently used to investigate food webs, to explore the extent to which common seal parasites feed directly on host tissue and fluids or absorb host-derived metabolites, which in turn may give an indication of their potential impact on the host's health. The trophic discrimination factor ΔN for the nasal mite, , was mostly positive, ranging between −0.
View Article and Find Full Text PDFVet Radiol Ultrasound
November 2024
Cross-sectional imaging is widely used to characterize adrenal gland tumors in humans. In small animal veterinary medicine, while some studies have attempted to distinguish between types of adrenal gland neoplasia using CT, peer-reviewed studies investigating canine adrenal glands on MRI are scant. This prospective, pilot, single-center, method comparison, cadaveric study aimed to assess the agreement between ex vivo MRI findings and analogous histopathological findings of the adrenal glands in dogs.
View Article and Find Full Text PDFTwo literature-known sulfido vanadates, Na[VS] and K[VS], were obtained through a straightforward and scalable synthetic method. Highly crystalline powders of both compounds were obtained from the homogeneous molten phases of starting materials via a─comparably rapid─solid-state technique. Low-temperature structure determination, ambient temperature powder diffraction, and solid-state NMR spectroscopy verify previous structural reports and indicate purity of the obtained samples.
View Article and Find Full Text PDFThe absorption features of optically generated, short-lived small bound electron polarons are inspected in congruent lithium tantalate, LiTaO(LT), in order to address the question whether it is possible to localize electrons at interstitial TaV:VLidefect pairs by strong, short-range electron-phonon coupling. Solid-state photoabsorption spectroscopy under light exposure and density functional theory are used for an experimental and theoretical access to the spectral features of small bound polaron states and to calculate the binding energies of the small bound TaLi4+(antisite) and TaV4+:VLi(interstitial site) electron polarons. As a result, two energetically well separated (ΔE≈0.
View Article and Find Full Text PDFThe tuning of second (SHG) and third (THG) harmonic emission is studied in the model system LiNb 1-xTa xO 3 (0≤x≤1, LNT) between the established edge compositions lithium niobate (LiNbO 3, x=0, LN) and lithium tantalate (LiTaO 3, x=1, LT). Thus, the existence of optical nonlinearities of the second and third order is demonstrated in the ferroelectric solid solution system, and the question about the suitability of LNT in the field of nonlinear and quantum optics, in particular as a promising nonlinear optical material for frequency conversion with tunable composition, is addressed. For this purpose, harmonic generation is studied in nanosized crystallites of mechanochemically synthesized LNT using nonlinear diffuse reflectometry with wavelength-tunable fundamental femtosecond laser pulses from 1200 nm to 2000 nm.
View Article and Find Full Text PDFIn the past 20 years in Switzerland, dogs with suspect acute leptospirosis frequently showed severe glomerular changes that had not been previously reported. These features were characterized by abundant extravasated erythrocytes and fewer neutrophils accompanied by marked fibrin exudation into the urinary space that was interpreted as an exudative glomerulonephritis (GN). This retrospective study describes this significant glomerular pathological change and investigates the association with leptospirosis.
View Article and Find Full Text PDFThe ternary sulfido bismuthate K[BiS] is synthesized in quantitative yields. The material exhibits nonlinear optical properties with strong second harmonic generation properties at arbitrary wavelengths in the infrared spectral range and a notable laser-induced damage threshold of 5.22 GW cm for pulsed laser radiation at a wavelength of 1040 nm, a pulse duration of 180 fs, and a repetition rate of 12.
View Article and Find Full Text PDFIn collaboration with the American College of Veterinary Pathologists.
View Article and Find Full Text PDFLysosomes are vital organelles vulnerable to injuries from diverse materials. Failure to repair or sequester damaged lysosomes poses a threat to cell viability. Here we report that cells exploit a sphingomyelin-based lysosomal repair pathway that operates independently of ESCRT to reverse potentially lethal membrane damage.
View Article and Find Full Text PDFA 2.5-year-old cat presented with progressive ataxia and lethargy. Magnetic resonance imaging (MRI) showed enlargement of the cerebellum and herniation of cerebellar vermis.
View Article and Find Full Text PDFNear-infrared (NIR) marker-based imaging is of growing importance for deep tissue imaging and is based on a considerable reduction of optical losses at large wavelengths. We aim to extend the range of NIR excitation wavelengths particularly to values beyond 1.6 μm in order to profit from the low loss biological windows NIR-III and NIR-IV.
View Article and Find Full Text PDFOptical breadboards with honeycomb structure provide a solid surface with mounting hole grids for building optical assemblies, sub-systems and experiments in the fields of quantum-optics and photonics. Performance criteria are the ability to resist bending under load (stiffness) and the ability to dissipate induced vibrations to the board (damping). The hardware presented in this paper deals with the possibility of assembling optical breadboards using 3D-printed building bricks with honeycomb structure, so-called 'breadboard bricks', and industrial aluminum extrusions, so-called 'breadboard profiles'.
View Article and Find Full Text PDFThe usability of the alkali niobates with their ferroelectric and photorefractive properties could be expanded if the development of synthesis methods would allow to obtain small, preferably monodispersed, crystals in the sub-μm to nanometer regime. Of all the possible synthesis methods, the most reliable is currently hydrothermal synthesis to generate small crystallite sizes of these materials. Although the products of sodium niobate are polydisperse and partially agglomerated, they show a significant SHG signal that is unexpectedly comparable to that of potassium niobate.
View Article and Find Full Text PDFActa Crystallogr B Struct Sci Cryst Eng Mater
December 2019
The complex trans-[RuNO(NH)F]SiF was synthesized in quantitative yield and the structure was characterized by X-ray diffraction and spectroscopic methods. The complex crystallizes in the non-centrosymmetric space group Pn. Hirshfeld surface analysis revealed that the dominant intermolecular interactions are of types H.
View Article and Find Full Text PDFVarious manifestations of small polarons strongly affect the linear and nonlinear optical properties of the oxide crystal lithium niobate ([Formula: see text], LN). While related transient absorption phenomena in LN have been extensively studied in recent decades, a sound microscopic picture describing the blue-green (photo)luminescence of lithium niobate single crystals is still missing. In particular, almost nothing is known about: (i) the luminescence build-up and (ii) its room temperature decay.
View Article and Find Full Text PDFBased on a model of coupled processes with differently time-dependent decay kinetics we present a critical review on photoluminescence (PL) and transient absorption (TA) experiments in undoped and Mg or Fe-doped LiNbO, together with a comprehensive interpretation of visible radiative and parallel non-radiative decay processes on timescales ranging from 50 ns up to minutes. Analogies and peculiarities of the kinetics of mobile self-trapped and pinned excitons are investigated and compared with those of hopping polarons in the same system. Exciton hopping with an activation energy of ≈0.
View Article and Find Full Text PDFLaser-based inspection of trivalent chromium conversion coatings on rough, cold-rolled aluminium substrates is studied from a basic physics perspective by means of angle and wavelength dependent measurements. As a result, we show that the correlation between the scattered laser light and the coating weight of the conversion layer is dominated by the phenomenon of interference. The combined experimental and numerical approach of our study is based on an appropriate layer model which was developed from a set of reference measurements of confocal microscopy, electron microscopy and X-ray photoelectron spectroscopy.
View Article and Find Full Text PDFToxoplasma gondii is a cosmopolitan zoonotic parasite and nowadays considered as an emerging neozoan pathogen in the marine environment. Cetacean innate immune reactions against T. gondii stages have not yet been investigated.
View Article and Find Full Text PDFThe structural and nonlinear optical properties of a new anilinium hybrid crystal of chemical formula (CHNCl·NO) have been investigated. The crystal structure was determined from single-crystal X-ray diffraction measurements performed at a temperature of 100 K which show that the compound crystallizes in a noncentrosymmetric space group (Pna2). The structural analysis was coupled with Hirshfeld surface analysis to evaluate the contribution of the different intermolecular interactions to the formation of supramolecular assemblies in the solid state that exhibit nonlinear optical features.
View Article and Find Full Text PDFJ Phys Condens Matter
February 2019
Transient absorption and photoluminescence are experimentally investigated in the polaronic reference system lithium niobate, LiNbO[Formula: see text] (LN), with the aim to refine the microscopic model of small polaron dynamics in materials with strong electron-phonon coupling. As a unique feature, our study is performed by using two different spectroscopic methods, in crystals with dopants enhancing photorefraction or damage resistance, and over a broad temperature range from 15-400 K. Although being self-consistent for particular experimental conditions, the hitherto used microscopic polaronic models reveal inconsistencies when applied to this larger data set.
View Article and Find Full Text PDFEnergy redistribution between two subpicosecond laser pulses of 2.5 eV photon energy is observed and studied in congruent, nominally undoped LiNbO, aiming to reveal the underlying coupling mechanisms. The dependences of pulse amplification on intensity, frequency detuning and pulse duration point to two different contributions of coupling, both based on self-diffraction from a recorded dynamic grating.
View Article and Find Full Text PDFNanocrystals of alkaline niobates are currently being discussed for various applications because of their diverse and remarkable properties. Although the growth of bulk niobate crystals is well established, little is known about respective nanocrystals and the optical properties of niobates below 100 nm. A systematic view of the hydrothermal synthesis of potassium niobate with respect to the precursor species reveals the sensitive dependence of the resulting crystalline phases and sizes on the educt modifications.
View Article and Find Full Text PDFCharge transport due to small polarons hopping among defective (bound polarons) and regular (free polarons) sites is shown to depend in a non-trivial way on the value of the stabilization energy provided by the lattice distortion surrounding the charge carriers. This energy, normally not directly accessible for bound polarons using spectroscopic techniques, is determined here by a combination of experimental and numerical methods for the important case of small electron polarons bound to [Formula: see text] defects in the prototype ferroelectric oxide lithium niobate. Our findings provide an estimation of the [Formula: see text] polaron stabilization energy [Formula: see text] and demonstrate that in lithium niobate both free and bound polarons contribute to charge transport at room temperature, explaining the fast decay of the light-induced bound polaron population observed by transient absorption spectroscopy.
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