Effect of blending of medium-temperature phase change material on the bitumen storage heat.

This study aims to investigate the feasibility of using D-Mannitol as a phase-change material (PCM) to increase the energy storage capacity and improve the thermomechanical characteristics of the modified bitumen. D-mannitol (Dm) was incorporated into Bitumen (Bm) using a high-speed shearing method. The results showed that the integration of PCM enhanced the physical characteristics of the basic bitumen, with the modified bitumen having a melting point close to that of D-mannitol (Tm = 164 °C).

Brominated flame retardants extraction from waste electrical and electronic equipment-derived ABS using supercritical carbon dioxide.

Persistent organic pollutants such as brominated flame retardants represent a major problem in the end-of-life of polymer materials. This study investigates the extraction of brominated flame retardants (BFR) from real waste electrical and electronic equipment (WEEE) using supercritical carbon dioxide (sc-CO). Sc-CO is a non-toxic solvent which possesses intermediate properties between liquids and gases which confer it high diffusivity and solubility.

Effect of Different Phosphate Glass Compositions on the Process-Induced Macromolecular Dynamics of Polyamide 66.

The present study provides a fundamental understanding of the mechanism of action of special new phosphate glass (P-glass) systems, having different glass transition temperatures (), in polyamide 66 (PA66). Dynamic mechanical analysis (DMA) revealed that the of PA66/low P-glass (ILT-1) was significantly shifted to a lower (65 °C), and another transition appeared at high temperature (166 °C). This was supported by a drop in the melting point and the crystallinity of the PA66/ILT-1 hybrid material as detected by differential scanning calorimetry (DSC).

Creep, recovery, and stress relaxation behavior of nanostructured bioactive calcium phosphate glass-POSS/polymer composites for bone implants studied under simulated physiological conditions.

The creep and recovery and the stress relaxation behaviors of poly(butylene adipate-co-terephthalate) (PBAT) and polyhydroxyalkanoates (PHA) binary blends incorporating 30 wt % of a mixture of trisilanolisobutyl polyhedral oligomeric silsesquioxanes (POSS) and calcium phosphate glass (CaP-g) were investigated under simulated physiological and human body temperature conditions. The synergistic effect of PHA and CaP-g/POSS filler remarkably improved the creep behavior of the PBAT matrix and decreased its residual strain, consequently enhancing its elastic recovery. A considerable increase of the relaxation modulus of the hybrid materials was also observed upon incorporation of PHA and CaP-g/POSS.

A simple method for tuning the glass transition process in inorganic phosphate glasses.

The physical modification of glass transition temperature (T(g)) and properties of materials via blending is a common practice in industry and academia and has a large economic advantage. In this context, simple production of hitherto unattainable new inorganic glass blends from already existing glass compositions via blending raises much hope with the potential to provide new glasses with new and improved properties, that cannot be achieved with classical glass synthesis, for a plethora of applications such as computers screens, glass-to-metal seals, and storage materials for nuclear wastes. Here, we demonstrate that blends of the specific glass compositions studied are miscible in all proportions, an unreported phenomenon in hard condensed matter like glass.