The exponential growth in textile fiber production and commensurate release of textile waste-based effluents into the environment has significant impacts on human wellbeing and the long-term planetary health. To abate these negative impacts and promote resource circularity, efforts are being made to recycle these waste materials via conversion into adsorbents for water decontamination. This review critically examines plant- and regenerated cellulose-based fibers for removing water pollutants such as heavy metals, dyes, pharmaceutical and petrochemical wastes.
View Article and Find Full Text PDFBio-based materials facilitate greener approach to engineering novel materials with multifunctional properties for various applications including water treatment. In this study, we extracted gliadin from wheat gluten using alcoholic solvent. The aggregation limitations of gliadin protein were overcome by functionalisation with metal oxides (MOs) TiO, AgFeO and AgFe-TiO prepared by chemical precipitations.
View Article and Find Full Text PDFVarious water treatment processes make extensive use of porous polymeric membranes. A key objective in membrane fabrication is to improve membrane selectivity without sacrificing other properties such as permeability. Herein, LiCl (0-2 wt.
View Article and Find Full Text PDFCommercially available ultrafiltration membranes were coated with cellulose nanofibers (CNFs) produced from softwood pulp by a two-step process: a non-derivatizing DES treatment and a simple mechanical treatment (high-speed homogenization and sonification). The CNFs coating aimed at enhancement of the removal of methylene blue (MB) from water and was investigated at different concentrations of the coating, quantified in grams of CNFs per square meter of the membrane (1.3, 6.
View Article and Find Full Text PDFDemand for sustainable packaging and building materials has increased the need for biobased additives. Biocomposites can often be exposed to different weather conditions and UV irradiation. Thus, additives to prevent the negative impact of weathering are generally added to composites.
View Article and Find Full Text PDFIn this study, wood-based cellulose-rich membranes were produced with a novel approach to casting procedure. Flat-sheet membranes were prepared from birch biomass pretreated with deep eutectic solvent and dissolved in ionic liquid-dimethylsulfoxide system via phase inversion method. Alkaline coagulation bath filled with sodium hydroxide solution was added to the process before a water coagulation bath and aimed to improve membranes' performance.
View Article and Find Full Text PDFUltrafiltration was employed in the purification of spent Deep Eutectic Solvent (DES, a mixture of choline chloride and lactic acid, 1:10, respectively) used in the extraction of lignin from lignocellulosic biomass. The aim of this was to recover different lignin fractions and to purify spent solvent. The results revealed that the commercial regenerated cellulose membranes-RC70PP and Ultracel 5 kDa UF membranes-could be used in the treatment of the spent DES.
View Article and Find Full Text PDFPharmaceutical blister packages usually comprise of aluminium and plastic layers. Due to their multi-material structure, the discarded packages are typically landfilled, although when separated, both metallic and polymeric fractions would be recyclable. In the present study, separation of aluminium and polymeric layers of waste pharmaceutical blisters was conducted by exploitation of deep eutectic solvent (DES, lactic acid - choline chloride) and pure lactic acid, both of which are considered green solvents.
View Article and Find Full Text PDFEnhancement of membrane permeability at no detriment of its other performances, e.g., selectivity, is a goal-directed objective in membrane fabrication.
View Article and Find Full Text PDFThe integration of highly efficient enzymatic catalysis with the solvation properties of ionic liquids for an environmentally friendly and efficient use of raw materials such as wood requires fundamental knowledge about the influence of relevant ionic liquids on enzymes. Switchable ionic liquids (SIL) are promising candidates for implementation of enzymatic treatments of raw materials. One industrially interesting SIL is constituted by monoethanol amine (MEA) and 1,8-diazabicyclo-[5.
View Article and Find Full Text PDFBackground: Pretreatment is a vital step upon biochemical conversion of lignocellulose materials into biofuels. An acid catalyzed thermochemical treatment is the most commonly employed method for this purpose. Alternatively, ionic liquids (ILs), a class of neoteric solvents, provide unique opportunities as solvents for the pretreatment of a wide range of lignocellulose materials.
View Article and Find Full Text PDFThe transformation of lignocellulosic materials into potentially valuable resources is compromised by their complicated structure. Consequently, new economical and feasible conversion/fractionation techniques that render value-added products are intensely investigated. Herein an unorthodox and feasible fractionation method of birch chips (B.
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