The induction of synthetic magnetic fields on lattice structures allows an effective control of their localization and transport properties. In this Letter, we generate effective π magnetic fluxes on a multiorbital diamond lattice, where first-order (S) and second-order (P) modes effectively interact. We implement a z-scan method on femtosecond-laser-written photonic lattices and experimentally observe Aharonov-Bohm caging for S and P modes, as a consequence of a band transformation and the emergence of a spectrum composed of three degenerated flat bands.
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