Antioxidant and antibacterial activities of Hibiscus Rosa-sinensis Linn flower extracts.

Antioxidant and antibacterial potential of different solvent extracts of locally grown Hibiscus rosa-sinensis Linn was evaluated. The antioxidant activity was assessed by estimation of total flavonoids contents, total phenolic contents, DPPH free radical scavenging activity and percentage inhibition of linoleic acid oxidation capacity. Agar disc diffusion method was used to assess antibacterial potential of crude extract of H.

Studies on molecular interactions of some sweeteners in water by volumetric and ultrasonic velocity measurements at T=(20.0-45.0°C).

Densities and ultrasonic velocity values for aqueous solutions of two sweeteners viz., maltose monohydrate and acesulfame-K have been measured as a function of concentration at 20.0-45.

Efficient synthesis of 2-amino-6-arylbenzothiazoles via Pd(0) Suzuki cross coupling reactions: potent urease enzyme inhibition and nitric oxide scavenging activities of the products.

In general, benzothiazole derivatives have attracted great interest due to thier pharmaceutical and biological importance. New 2-amino-6-arylbenzothiazoles were synthesized in moderate to excellent yields via Suzuki cross coupling reactions using various aryl boronic acids and aryl boronic acid pinacol esters and the antiurease and nitric oxide (NO) scavenging activity of the products were also examined. The most active compound concerning urease enzyme inhibition was 6-phenylbenzo[d]thiazole-2-amine 3e, with an IC₅₀ value of 26.

6-Bromo-1-methyl-4-[2-(1-phenyl-ethyl-idene)hydrazinyl-idene]-3,4-dihydro-1H-2λ(6),1-benzothia-zine-2,2-dione.

In the title compound, C(17)H(16)BrN(3)O(2)S, the dihedral angle between the aromatic rings is 1.24 (15)° and the C=N-N=C torsion angle is 167.7 (3)°.

In vitro antimicrobial, antioxidant, cytotoxicity and GC-MS analysis of Mazus goodenifolius.

The antimicrobial, antioxidant and cytotoxic properties of Mazus goodenifolius (Hornem.) Pennell essential oil, methanol extract and some solvent-extracted subfractions of the latter were appraised. A qualitative, quantitative analysis of the classes of phytochemicals in the various fractions and GC-MS analysis of the essential oil was carried out.

2-{[2-(1-Methyl-2,2-dioxo-3,4-dihydro-1H-2λ(6),1-benzothia-zin-4-yl-idene)hydrazin-1-yl-idene]meth-yl}phenol.

In the title compound, C(16)H(15)N(3)O(3)S, the dihedral angle between the aromatic rings is 8.18 (11)° and the C=N-N=C torsion angle is 178.59 (14)°.

1-Ethyl-4-[1-(1-phenyl-ethyl-idene)hydrazin-2-yl-idene]-3,4-dihydro-1H-2λ(6),1-benzothia-zine-2,2-dione.

In the title compound, C(18)H(19)N(3)O(2)S, the thia-zine ring adopts an envelope conformation, with the S atom displaced by 0.732 (1) Å from the other atoms of the ring. The phenyl ring is oriented at a dihedral angle of 79.

3,4-Dimethyl-2-(2-oxo-2-phenyl-eth-yl)-2H,4H-pyrazolo-[4,3-c][1,2]benzothia-zine-5,5-dione.

In the title mol-ecule, C(19)H(17)N(3)O(3)S, the heterocyclic thia-zine ring adopts a half-chair conformation with the S and N atoms displaced by 0.530 (5) and 0.229 (6) Å, respectively, on opposite sides of the mean plane formed by the remaining ring atoms.

Prediction of robustly large molecular second-order nonlinear optical properties of terpyridine-substituted hexamolybdates: structural modelling towards a rational entry to NLO materials.

We have explored an innovative, versatile, and novel molecular hybrid containing polyoxometalate (POM) cluster linked with terpyridine ligand via pi-bridged donor-acceptor (D-A) configuration. The dipole polarizabilities, density of states, and second-order nonlinear optical (NLO) properties of terpyridine-substituted hexamolybdates have been investigated by using time-dependent density functional response theory (TDDFT). This class of organic-inorganic hybrid compounds possesses a robustly large molecular second-order NLO response, especially [Mo(6)O(18)(N(4)C(25)H(16)I(2))](2-) (system 5) and [Mo(6)O(17)(N(4)C(25)H(16)(CN)(2))(N(4)C(25)H(16)(CN)(2))](2-) (system 10) with the static second-order polarizability (beta(vec)) computed to be 1209.

2-[2-(3-Chloro-phen-yl)-2-oxoeth-yl]-1,2-benzisothia-zol-3(2H)-one 1,1-dioxide.

In the title compound, C(15)H(10)ClNO(4)S, the benzothia-zole ring system is essentially planar [maximum deviation = 0.0382 (13) Å for the N atom] and forms a dihedral angle of 74.43 (6)° with the chloro-substituted benzene ring.

2-(2-Oxo-2-phenyl-ethyl)-1,2-benziso-thia-zol-3(2H)-one 1,1-dioxide.

In the title compound, C(15)H(11)NO(4)S, the benzothia-zole unit is essentially planar [maximum deviation = 0.0644 (14) Å for the N atom] and forms a dihedral angle 54.43 (6)° with the phenyl ring.