Iron alginate beads (Fe-Alg) were prepared, characterized and implemented for the degradation of amoxicillin (AMX) by the heterogeneous electro-Fenton process using a graphite cathode recovered from used batteries. Scanning electron microscopy (SEM) showed that (Fe-Alg) beads have a spherical shape and the results of energy dispersive spectrometric (EDS) revealed the presence of iron in (Fe-Alg). Optimization of the operating parameters showed that a complete degradation of AMX was achieved within 90 min of heterogeneous electro-Fenton treatment by operating under these conditions: initial AMX concentration: 0.
View Article and Find Full Text PDFTiO(P25) has been widely used to treat wastewater; however, the elimination of TiO(P25) suspended in the treated water causes running costs and induces secondary pollution, which greatly restricts its practical applications. Consequently, several methods have been implemented to immobilize TiO(P25) on various substrates. This work deals with the immobilization of TiO(P25) in chitosan film by using the cross-linking method.
View Article and Find Full Text PDFIn this study, peroxydisulfate (PDS) was successfully activated by UV-irradiation for the degradation of paracetamol (PCT) frequently detected in the environment. Results showed that increasing the initial PDS concentration from 5 to 20 mM promote the removal of PCT from 49.3% to 97.
View Article and Find Full Text PDFThe use of waste and by-products locally available in large quantities and at low cost as adsorbents can be considered an appropriate approach for improving waste management and protecting the environment. Cotton textile waste was used to prepare adsorbents (MC) via pyrolysis followed by a chemical modification with H PO . MC samples were characterized by scanning electron microscopy, FTIR spectroscopy, and N adsorption-desorption isotherm.
View Article and Find Full Text PDFIn this study, the degradation of paracetamol (PCT) by thermo-activated peroxydisulfate (PDS) and the feasibility of coupling thermo-activated peroxydisulfate to activated sludge culture were examined. The effect of the relevant parameters on the thermo activated peroxydisulfate process, namely temperature, PDS concentration, initial pH and initial PCT concentration was investigated. As observed, the solution pH did not have a significant effect on the PCT degradation.
View Article and Find Full Text PDFThis paper presents a new sorbent, agar-agar (AA), impregnated on porous activated carbon (AC) - and its Pb(II) sorption properties. The influence of impregnation ratio (AA/AC) on the Pb(II) ion sorption properties is studied in order to optimize this parameter. The developed AC-AA shows substantial capability to sorb Pb(II) ions from aqueous solutions and 75% represents the optimal impregnation ratio.
View Article and Find Full Text PDFIn this paper, the major factors affecting the degradation and the mineralization of sulfamethazine by Electro/Fe/peroxydisulfate (PDS) process (e.g. current density, PDS concentration, Fe ions concentration and initial sulfamethazine (SMT) concentration) were evaluated.
View Article and Find Full Text PDFThe removal of tetracycline (TC) by electro/Fe/peroxydisulfate process combined to the biological treatment is reported in this study. Effect of current density, peroxydisulfate (PDS) concentration, Fe ions concentration and initial tetracycline concentration were investigated. The results indicated that the removal efficiency of TC increased with increasing current density and decreases with tetracycline initial concentration.
View Article and Find Full Text PDFThe purpose of this study was first to examine the electrochemical oxidation of two antibiotics, tetracycline (TC) and tylosin (Tylo), considered separately or in mixture, on a glassy carbon electrode in aqueous solutions; and then to assess the relevance of such electrochemical process as a pre-treatment prior to a biological treatment (activated sludge) for the removal of these antibiotics. The influence of the working potential and the initial concentration of TC and Tylo on the electrochemical pre-treatment process was also investigated. It was noticed that antibiotics degradation was favoured at high potential (2.
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