A review on bioactivity, plant safety, and metal-reducing potential of lignin, its micro/nanostructures, and composites.

Modern science focuses on sustainability-oriented innovation. Structurally sophisticated lignin is a sustainable alternative to non-renewable resources. Over the last several years, a tremendous scientific effort has been made to innovate lignin-based sustainable materials for numerous advanced applications.

Controlled release of bioactive copper (I) acylthiourea complexes through immobilization onto electrospun PCL/lignin nanofibers.

This study presents the first development of Cu (I) acylthiourea complexes (C1-C5) incorporated polycaprolactone/lignin (PCL/Lig) electrospun nanofiber composites (PCL/Lig@Cu(I)). Electrospinning conditions and mass ratios of PCL and lignin were optimized, followed by the incorporation of varying concentrations of Cu(I) complexes. Structural, morphological, and thermal properties were characterized using SEM, TEM, FT-IR, XRD, TGA and WCA analyses.

Design and Characterization of Polyvinyl Alcohol/Kappa-Carrageenan Pickering Emulsion Biocomposite Films for Potential Wound Care Applications.

This study aimed to develop polyvinyl alcohol (PVA) and kappa-carrageenan (κCA) biocomposite films using a Pickering emulsion technique for wound care applications. Juniper essential oil and modified sepiolite were incorporated to enhance functionality, with films prepared via solvent casting and characterized for structural, thermal, and mechanical properties. The PCOS-2 film exhibited the highest mechanical performance, with Young's modulus of 6.

Fabrication of Multifunctional Tents Using Canvas Fabric.

Herein, this study was compiled to investigate a suitable solution for the fabrication and development of the multifunctional defense tent from previously reported research. The military always needs to protect their soldiers and equipment from detection. The advancement of infrared detection technology emphasizes the significance of infrared camouflage materials, reducing thermal emissions for various applications.

Sustainable bioactive food packaging based on electrospun zein-polycaprolactone nanofibers integrated with aster yomena extract loaded halloysite nanotubes.

Compostable zein-polycaprolactone (PZ) electrospun nanofiber integrated with different concentrations of Aster yomena extract loaded halloysite nanotubes (A. yomena-HNT) as bioactive nanofibrous food packaging is reported. SEM micrographs reveal heterogeneous nanofibers.

Eggshell membrane as a novel and green platform for the preparation of highly efficient and reversible curcumin-based colorimetric sensor for the monitoring of chicken freshness.

Herein, for the very first time, we report a paper-like biomass, eggshell membrane (ESM), as a suitable platform for the fabrication of a colorimetric sensor (E-Cot). Green ethanolic extract, curcumin (CUR), was used as a sensing material to coat with the ESM. The present E-Cot effectively changed its color (yellow to red) in the real-time monitoring for chicken spoilage.

"Micro-to-nano": Reengineering of jute for constructing cellulose nanofibers as a next-generation biomaterial.

Micro-to-nano transformation can make a material unique. This research uses jute microfiber to extract Holo and Alpha forms of cellulose, which are later attempted to electrospun into superfine nanofibers (NFs). Initial investigation of morphological, physicochemical, crystallographic, and thermal properties confirmed successful synthesis of Holo and Alpha-cellulose (H/A-cellulose).

Antibacterial Activity of Molybdenum Oxide-Polyacrylonitrile Composite Membrane with Fast Silver Ion Reduction.

The development of hybrid composite antibacterial agents for wound dressing has garnered significant attention due to their remarkable antibacterial efficacy and their potential to mitigate microbial resistance. In this study, we present an approach to designing and fabricating wound dressing membranes, utilizing molybdenum oxide-polyacrylonitrile (MoO/PAN) hybrid composites through electrospinning. Subsequently, we enhanced the membrane's effectiveness by introducing silver (Ag@MoO/PAN) into the matrix via a rapid (within one min) green synthesis method under UV irradiation.

Fast Energy Storage of SnS Anode Nanoconfined in Hollow Porous Carbon Nanofibers for Lithium-Ion Batteries.

The development of conversion-typed anodes with ultrafast charging and large energy storage is quite challenging due to the sluggish ions/electrons transfer kinetics in bulk materials and fracture of the active materials. Herein, the design of porous carbon nanofibers/SnS composite (SnS @N-HPCNFs) for high-rate energy storage, where the ultrathin SnS nanosheets are nanoconfined in N-doped carbon nanofibers with tunable void spaces, is reported. The highly interconnected carbon nanofibers in three-dimensional (3D) architecture provide a fast electron transfer pathway and alleviate the volume expansion of SnS , while their hierarchical porous structure facilitates rapid ion diffusion.

A Review on Electrospun Nanofiber Composites for an Efficient Electrochemical Sensor Applications.

The present review article discusses the elementary concepts of the sensor mechanism and various types of materials used for sensor applications. The electrospinning method is the most comfortable method to prepare the device-like structure by means of forming from the fiber structure. Though there are various materials available for sensors, the important factor is to incorporate the functional group on the surface of the materials.

Electrospun composite nanofibers of deoxyribonucleic acid and polylactic acid for skincare applications.

The development of useful biomaterials has resulted in significant advances in various fields of science and technology. The demand for new biomaterial designs and manufacturing techniques continues to grow, with the goal of building a sustainable society. In this study, two types of DNA-cationic surfactant complexes were synthesized using commercially available deoxyribonucleic acid from herring sperm DNA (hsDNA, <50 bp) and deoxyribonucleic acid from salmon testes DNA (stDNA, ~2000 bp).

Proton-conductive aromatic membranes reinforced with poly(vinylidene fluoride) nanofibers for high-performance durable fuel cells.

Durability and ion conductivity are counteracting properties of proton-conductive membranes that are challenging to achieve simultaneously and determine the lifetime and performance of proton exchange membrane fuel cells. Here, we developed aromatic ionomers reinforced with nonwoven poly(vinylidene fluoride) (PVDF) nanofibers. Because of the right combination of an isotropic nonwoven PVDF with high porosity (78%) and partially fluorinated aromatic ionomers (SPP-TFP-4.

Fabrication of Electrospun PVA/Zein/Gelatin Based Active Packaging for Quality Maintenance of Different Food Items.

In this research, electrospun PVA/Zein/Gelatin based tri-component active food packaging has been fabricated to enhance the shelf life of food by assuring the food quality (freshness, taste, brittleness, color, etc.) for longer. Electrospinning imparts good morphological properties along with breathability in nanofibrous mats.

The Effect of Polymeric Nanofibers Used for 3D-Printed Scaffolds on Cellular Activity in Tissue Engineering: A Review.

Promising scaffolds for developing advanced tissue engineering architectures have emerged in recent years through the use of nanofibers and 3D printing technologies. Despite this, structural integrity and cell proliferation are highlighted as fundamental challenges for design scaffolds and future prospects. As a biomimetic scaffold, the nanofiber-reinforced hydrogels demonstrated a better compressive modulus and cell growth.

Lignin-facilitated growth of Ag/CuNPs on surface-activated polyacryloamidoxime nanofibers for superior antibacterial activity with improved biocompatibility.

Introduction: Nanofibers are one of the role-playing innovations of nanotechnology. Their high surface-to-volume ratio allows them to be actively functionalized with a wide range of materials for a variety of applications. The functionalization of nanofibers with different metal nanoparticles (NPs) has been studied widely to fabricate antibacterial substrates to battle antibiotic-resistant bacteria.

PVA/Inulin-Based Sustainable Films Reinforced with Pickering Emulsion of Niaouli Essential Oil for Potential Wound Healing Applications.

In this study, sustainable water-based films were produced via the solvent-casting method. Petroleum-free-based polyvinyl alcohol (PVA) and carbohydrate-based inulin (INL) were used as matrices. Vegetable-waste pumpkin powder was used in the study because of its sustainability and antibacterial properties.

Synthesized bioactive lignin nanoparticles/polycaprolactone nanofibers: A novel nanobiocomposite for bone tissue engineering.

The use of artificial biomaterial with enhanced bioactivity for osteostimulation is a major research concern at present days. In this research, antibacterial and osteostimulative core-shell lignin nanoparticles (LgNP) were synthesized from alkali lignin using tetrahydrofuran (THF) as solvent via a simultaneous pH and solvent shifting technology. Later, LgNP-loaded polycaprolactone (PCL) composite nanofibers were fabricated via the electrospinning technique.

Electrospun Composite Nanofibers for Functional Applications.

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Introducing Deep Eutectic Solvents as a Water-Free Dyeing Medium for Poly (1,4-cYclohexane Dimethylene Isosorbide Terephthalate) PICT Nanofibers.

Water, one of the most priceless sources of life, is becoming dangerously threatened and contaminated due to population growth, industrial development, and climatic variations. The drainage of industrial, farming, and municipal sewage into drinking water sources pollutes the water. The textile processing industry is one of the major consumers of water.

Fabrication of Poly(Ethylene-glycol 1,4-Cyclohexane Dimethylene-Isosorbide-Terephthalate) Electrospun Nanofiber Mats for Potential Infiltration of Fibroblast Cells.

Recently, bio-based electrospun nanofiber mats (ENMs) have gained substantial attention for preparing polymer-based biomaterials intended for use in cell culture. Herein, we prepared poly(ethylene-glycol 1,4-Cyclohexane dimethylene-isosorbide-terephthalate) (PEICT) ENMs using the electrospinning technique. Cell adhesion and cell viability of PEICT ENMs were checked by fibroblast cell culture.

Fabricating Antibacterial and Antioxidant Electrospun Hydrophilic Polyacrylonitrile Nanofibers Loaded with AgNPs by Lignin-Induced In-Situ Method.

Concerning the environmental hazards owing to the chemical-based synthesis of silver nanoparticles (AgNPs), this study aimed to investigate the possibility of synthesizing AgNPs on the surface polyacrylonitrile (PAN) nanofibers utilizing biomacromolecule lignin. SEM observations revealed that the average diameters of the produced nanofibers were slightly increased from ~512 nm to ~673 nm due to several factors like-swellings that happened during the salt treatment process, surface-bound lignin, and the presence of AgNPs. The presence of AgNPs was validated by transmission electron microscope (TEM) and X-ray photoelectron spectroscopy (XPS) analysis.

Synthesis of Highly Conductive Electrospun Recycled Polyethylene Terephthalate Nanofibers Using the Electroless Deposition Method.

Plastic bottles are generally recycled by remolding them into numerous products. In this study, waste from plastic bottles was used to fabricate recycled polyethylene terephthalate (r-PET) nanofibers via the electrospinning technique, and high-performance conductive polyethylene terephthalate nanofibers (r-PET nanofibers) were prepared followed by copper deposition using the electroless deposition (ELD) method. Firstly, the electrospun r-PET nanofibers were chemically modified with silane molecules and polymerized with 2-(methacryloyloxy) ethyl trimethylammonium chloride (METAC) solution.

Evaluating Antibacterial Efficacy and Biocompatibility of PAN Nanofibers Loaded with Diclofenac Sodium Salt.

Side effects of the drugs' oral administration led us to examine the possibility of using diclofenac sodium (DLF) in a polymeric drug delivery system based on electrospun polyacrylonitrile (PAN) nanofibers, which can be produced cost-effectively and with good applicability for transdermal treatments. The inclusion of DLF in PAN nanofibers increased the nanofiber diameter from ~200 nm to ~500 nm. This increase can be attributed to the increase in the spinning solution viscosity.

Carboxymethyl Cellulose (CMC) Based Electrospun Composite Nanofiber Mats for Food Packaging.

Cellulose is one of the most abundantly available natural polymers. Carboxymethyl cellulose (CMC) belongs to the cellulose family and has different degrees of substitution. Current research comprises the fabrication and characterization of CMC nanofibers using polyvinyl alcohol (PVA) and polyvinylpyrrolidone (PVP) as capping agents and carriers for sustainable food packaging applications.

Lignin-mediated in-situ synthesis of CuO nanoparticles on cellulose nanofibers: A potential wound dressing material.

Herein we present our research on the synthesis of CuO nanoparticles on the surface of electrospun cellulose (CE) nanofibers using alkali lignin as a reducing agent. Fascinatingly, CA nanofibers were deacetalized during alkali lignin treatment, which was verified by FTIR-ATR spectra. The morphology of the produced nanofibers was observed with SEM and TEM.