To obtain high efficient elimination of ammonia (NH) from wastewater, Cu(II), Ni(II), and Co(II)) were loaded on Dowex-50WX8 resin (D-H) and studied their removal efficiency towards NH from aqueous solutions. The adsorption capacity of Cu(II)-loaded on D-H (D-Cu) towards NH (q = 95.58 mg/g) was the highest one compared with that of D-Ni (q = 57.
View Article and Find Full Text PDFPharmaceutics
October 2023
Objective: To assess and compare the effects of two pediatric anti-asthmatic medication doses on the microhardness of enamel and microhardness, surface roughness and color of restorative materials.
Methods: Human enamel samples and packable and flowable composite restorations were used. The samples were exposed to Salbutamol (0.
Natural resources including sand are one of the best approaches for treating dye-polluted wastewater. The SiO/PANI-SDS nanocomposite was synthesized by self-assembly and intermolecular interaction. The physicochemical features of the SiO/PANI-SDS nanocomposite were explored by FT-IR, XRD, SEM, TEM, EDX, and N adsorption-desorption techniques to be evaluated as an adsorbent for the MB.
View Article and Find Full Text PDFCationic ligand exchange is one of the most predominant mechanisms for the removal of ammonia from wastewater through complex formation. The complexation technique occurs between the metal ions loaded on the surface of Amberlite IR-120 and ammonia which is present in the medium. Cu(II)-loaded Amberlite IR-120 (R-Cu) was prepared and described using FT-IR, TGA, SEM, and EDX techniques.
View Article and Find Full Text PDFA comparison study examines six different metal oxides (CuO, ZnO, FeO, CoO, NiO, and α-MnO) for the degradation of malachite green dye using four distinct processes. These processes are as follows: sonocatalysis (US/metal oxide), sonocatalysis under ultra-violet irradiation (US/metal oxide/UV), sonocatalysis in the presence of hydrogen peroxide (US/metal oxide/HO), and a combination of all these processes (US/metal oxide/UV/HO). The effective operating parameters, such as the dosage of metal oxide nanoparticles (MONPs), the type of the process, and the metal oxides' efficiency order, were studied.
View Article and Find Full Text PDFJ Musculoskelet Neuronal Interact
December 2019
Objective: To evaluate the effect of simultaneous proprioceptive - visual training on gait parameters in children with spastic diplegic cerebral palsy.
Method: Gait parameters of 30 spastic diplegic children (age range 4-6 years) were evaluated before and after treatment by Tekscan's Walkway Pressure system. They were randomly and equally assigned into two groups (study and control).
Spectrochim Acta A Mol Biomol Spectrosc
February 2020
The kinetics of the homogeneous and heterogeneous catalytic oxidation processes of three azo dyes in presence of copper (II) - ions, copper (II) - ions - supported on alumina and on zinc oxide as well as copper ammonia complex supported on alumina were investigated in aqueous solutions. The dyes are Chromotrope 2B (C2B), Chromotrope 2R (C2R) and Chrysophenen (CRY). The reaction progress was followed by monitoring the decrease in absorbance at ℷmax 512, 511 and 401 nm, respectively.
View Article and Find Full Text PDFThe fluorescence quenching N,N-bis(2,6-dimethylphenyl)-3,4:9,10-perylenetetra-carboxylic diimide (BDPD) by colloidal silver nanoparticles (AgNPs) was studied in methanol and ethylene glycol by steady state fluorescence measurements. The Stern-Volmer quenching rate constant (Ksv) was calculated as 8.1 × 10(8) and 8.
View Article and Find Full Text PDFThe spectral and photophysical properties of a new chalcone derivative (2E)-3-[4-(dimethylamino) phenyl]-1-(naphthalen-1-yl) prop-2-en-1-one (DPNP) containing donor-acceptor group has been synthesized and characterized on the basis of the spectral (IR, (1)HNMR & (13)C NMR) and X- ray crystallographic data. The effect of solvents on photophysical parameters such as singlet absorption, molar absorptivity, oscillator strength, dipole moment, fluorescence spectra, and fluorescence quantum yield of DPNP have been investigated comprehensively. Significant red shift was observed in the emission spectrum of DPNP compared to the absorption spectrum upon increasing the solvent polarity, indicating a higher dipole moment in the excited state than in the ground state.
View Article and Find Full Text PDFSpectrochim Acta A Mol Biomol Spectrosc
March 2015
The kinetics of decolorization of Chromotrope 2R (C2R) was studied spectrophotometrically using the montmorilloniteK10-Cu(II)ethylenediamine composite (MMTK10-Cu(en)2) as catalyst and H2O2 as oxidant in aqueous solution. The catalyst was prepared and characterized by SEM, FTIR, XRD and TGA techniques. The dependence of reaction rate on H2O2 concentration was examined under UV irradiation in the presence and absence of the catalyst, and in the presence of the catalyst without the UV irradiation.
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