Preventing Alloy Electrocatalyst Segregation in Air Using Sacrificial Passivating Overlayers.

Many alloy electrocatalysts, including intermetallics, are exceptionally sensitive to segregation in air due to the electronic dissimilarity of the constituent metals. We demonstrate that even alloys with strong cohesive energies rapidly segregate upon air exposure, completely burying the less reactive constituent metal beneath the surface. To circumvent this issue, we develop and validate a new experimental approach for bridging the pressure gap between electronic structure characterization performed under ultrahigh vacuum and electrocatalytic activity testing performed under ambient conditions.