The sol-gel transition of fat-free milk by acidification was studied with neutron scattering experiments and Monte Carlo simulations. Spin-echo small angle neutron scattering (SESANS) and ultrasmall angle neutron scattering (USANS) experiments were performed to measure the static structure of milk and yogurt, as well as the aggregation kinetics. Colloidal gelation was simulated from a reaction limited domain (RLCA) to the diffusion limited regime (DLCA) as cluster-cluster aggregation of adhesive, hard spheres on a three-dimensional lattice.
View Article and Find Full Text PDFPhys Rev E Stat Nonlin Soft Matter Phys
May 2008
Spin-echo small-angle neutron scattering is able to characterize powders in terms of their density-density correlation function. Here we present a microstructural study on a fine cohesive powder undergoing uniaxial compression. As a function of compression, we measure the autocorrelation function of the density distribution.
View Article and Find Full Text PDFWe present inelastic neutron scattering measurements on liquid mercury at room temperature for wave numbers q in the range 0.3 View Article and Find Full Text PDF
We show that weak bonds are responsible for the way a molecule is held in a zeolite, and for its reactivity.
View Article and Find Full Text PDFWe evaluate the linear term in the density expansion of the dynamic structure factor for a classical gas using a generalized Enskog theory developed by one of the authors, which enables us to describe the dynamics at small time and length scales where the use of the Boltzmann equation is severely limited. Agreement of the theory with experiment and simulation is very good. We find that the linear term is very sensitive to the shape of the potential so that the dynamic structure factor can serve as a good probe to determine the intermolecular potentials of dilute gases.
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