Publications by authors named "I F Popov"

Atomic-scale changes can significantly impact heterogeneous catalysis, yet their atomic mechanisms are challenging to establish using conventional analysis methods. By using identical location scanning transmission electron microscopy (IL-STEM), which provides quantitative information at the single-particle level, we investigated the mechanisms of atomic evolution of Ru nanoclusters during the ammonia decomposition reaction. Nanometre-sized disordered nanoclusters transform into truncated nano-pyramids with stepped edges, leading to increased hydrogen production from ammonia.

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The human body can be viewed as a combination of ecological niches inhabited by trillions of bacteria, viruses, fungi, and parasites, all united by the microbiota concept. Human health largely depends on the nature of these relationships and how they are built and maintained. However, personal hygiene practices have historically been focused on the wholesale elimination of pathogens and "hygiene-challenging microorganisms" without considering the collateral damage to beneficial and commensal species.

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Article Synopsis
  • The study investigates hantaviruses in bats, specifically focusing on common noctules and other bat species from Rostov Bat Rehabilitation Center in Russia.
  • Hantaviruses were detected in 4.94% of blood samples and 1.1% of fecal samples from common noctules, suggesting these bats can harbor these viruses.
  • Phylogenetic analysis indicates that the detected viruses are closely related to Loanvirus brunaense, previously identified in Central European bats, highlighting the potential for these viruses to be species-specific and geographically widespread.
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Polymer-in-salt electrolytes were introduced three decades ago as an innovative solution to the challenge of low Li-ion conductivity in solvent-free solid polymer electrolytes. Despite significant progress, the approach still faces considerable challenges, ranging from a fundamental understanding to the development of suitable polymers and salts. A critical issue is maintaining both the stability and high conductivity of molten salts within a polymer matrix, which has constrained their further exploration.

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Article Synopsis
  • The reaction of Cp*(TerN)UI with KC produces the first known stable trivalent uranium imido complex, known as KCp*(TerN)UI.
  • This compound is significant because trivalent uranium imidos have been difficult to isolate and are usually unstable.
  • Both experimental and computational studies suggest that the coordination with potassium (K) is key to stabilizing this U(III) monoimido complex.
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