A facile route to synthesize n-SnO/p-CuFeO to rapidly degrade toxic methylene blue dye under natural sunlight.

In the present study, the n-SnO/p-CuFeO (p-CFO) complex was prepared by a two-step process. p-CFO synthesized by the molten salt method was coated with SnO synthesized by a facile chemical precipitation method. The formation of n-SnO/p-CFO was confirmed by powder X-ray diffraction (PXRD).

Colorimetric and fluorimetric detection of fluoride ion using thiazole derived receptor.

Thiazole based receptor 3, was designed and synthesized by condensation reactionof5-chlorosalicylaldehyde with 4-(4-phenylthiazol-2-yl)semicarbazide for colorimetric and fluorimetric detection of fluoride ion. Receptor 3 was characterized by H NMR, C NMR, and HRMS, and shows absorption in 280-400 nm region with emission at 442 nm in tetrahydrofuran (THF). Addition of fluoride ion to the THF solution of receptor 3 results in color change from colorless to yellow with significant change in UV-Visible absorption.

A novel amperometric catechol biosensor based on α-FeO nanocrystals-modified carbon paste electrode.

In this work, we designed an amperometric catechol biosensor based on α-FeO nanocrystals (NCs) incorporated carbon-paste electrode. Laccase enzyme is then assembled onto the modified electrode surface to form a nanobiocomposite enhancing the electron transfer reactions at the enzyme's active metal centers for catechol oxidation. The biosensor gave good sensitivity with a linear detection response in the range of 8-800 μM with limit of detection 4.

Tunneling magnetoresistance with sign inversion in junctions based on iron oxide nanocrystal superlattices.

Magnetic tunnel junctions sandwiching a superlattice thin film of iron oxide nanocrystals (NCs) have been investigated. The transport was found to be controlled by Coulomb blockade and single-electron tunneling, already at room temperature. A good correlation was identified to hold between the tunnel magnetoresistance (TMR), the expected magnetic properties of the NC arrays, the charging energies evaluated from current-voltage curves, and the temperature dependence of the junction resistance.

Room-temperature tunnel magnetoresistance and spin-polarized tunneling through an organic semiconductor barrier.

Electron spin-polarized tunneling is observed through an ultrathin layer of the molecular organic semiconductor tris(8-hydroxyquinolinato)aluminum (Alq3). Significant tunnel magnetoresistance (TMR) was measured in a Co/Al2O3/Alq3/NiFe magnetic tunnel junction at room temperature, which increased when cooled to low temperatures. Tunneling characteristics, such as the current-voltage behavior and temperature and bias dependence of the TMR, show the good quality of the organic tunnel barrier.