Nanostructured composite particles of nano- and submicron sizes were synthesized by a combination of sol-gel and sonochemical techniques. Their graphene content was 0.8-0.
View Article and Find Full Text PDFAluminum matrix composites reinforced with multiwalled carbon nanotubes (MWCNTs) are promising materials for applications in various high-tech industries. Control over the processes of interfacial interaction in Al/MWCNT composites is important to achieve a high level of mechanical properties. The present study describes the effects of coating MWCNTs with titanium carbide nanoparticles on the formation of mechanical properties and the evolution of the reinforcement structure in bulk aluminum matrix nanocomposites with low concentrations of MWCNTs under conditions of solid-phase consolidation of ball-milled powder mixtures.
View Article and Find Full Text PDFA phenomenological description of nondegenerate and degenerate three-wave mixing in the bulk of an isotropic chiral medium is given for the wide class of fundamental light beams with nonuniform polarization distribution and multimode transverse structure. Special attention is paid to the classical and quantum interpretation of interconversion between spin and orbital parts of the angular momentum of the input and output beams.
View Article and Find Full Text PDFPhase diagrams of carbon, and those focusing on the graphite-to-diamond transitional conditions in particular, are of great interest for fundamental and applied research. The present study introduces a number of experiments carried out to convert graphite under high-pressure conditions, showing a formation of stable phase of fullerene-type onions cross-linked by sp-bonds in the 55-115 GPa pressure range instead of diamonds formation (even at temperature 2000-3000 K) and the already formed diamonds turn into carbon onions. Our results refute the widespread idea that diamonds can form at any pressure from 2.
View Article and Find Full Text PDFNanodiamond in a 2-5-nm size interval (which is typical for an appearance of quantum confinement effect) show Raman spectra composed of 3 bands at 1325, 1600, and 1500 cm (at the 458-nm laser excitation) which shifts to 1630 cm at the 257-nm laser excitation. Contrary to sp-bonded carbon, relative intensities of the bands do not depend on the 458- and 257-nm excitation wavelengths, and a halfwidth and the intensity of the 1600 cm band does not change visibly under pressure at least up to 50 GPa. Bulk modulus of the 2-5-nm nanodiamond determined from the high-pressure study is around 560 GPa.
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