Ammonia is a promising carbon-free hydrogen carrier. Owing to their nickel-rich anodes and high operating temperatures, solid oxide fuel cells (SOFCs) can directly utilize NH fuel-direct-ammonia SOFCs (DA-SOFCs). Lowering the operating temperature can diversify application areas of DA-SOFCs.
View Article and Find Full Text PDFGrowing global water demand has brought desalination technologies to the forefront for freshwater production from nontraditional water sources. Among these, forward osmosis (FO) is a promising two-step desalination process (draw dilution and regeneration), but it is often overlooked due to the energy requirements associated with draw regeneration. To address this limiting factor, we demonstrate FO desalination using thermally responsive ionic liquids (ILs) that are regenerated using a renewable energy input, that is, solar heat.
View Article and Find Full Text PDFHerein, we present a scalable approach for the synthesis of a hydrogen-bonded organic-inorganic framework via coordination-driven supramolecular chemistry, for efficient remediation of trace heavy metal ions from water. In particular, using copper as our model ion of interest and inspired by nature's use of histidine residues within the active sites of various copper binding proteins, we design a framework featuring pendant imidazole rings and copper-chelating salicylaldoxime, known as zinc imidazole salicylaldoxime supramolecule. This material is water-stable and exhibits unprecedented adsorption kinetics, up to 50 times faster than state-of-the-art materials for selective copper ion capture from water.
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