We report a nanoscale morphology-regulation strategy of self-assembled double-hydrophilic block copolymers with square planar Pt compounds. The selective coordination of Pt on the chelating blocks of poly(acrylic acid)--poly(ethylene glycol) (PAA--PEG) induced the self-association of metal-chelated unimers by the known cohesive force of Pt. The block-length variation of PAA with constant PEG led to the shape transition from normal core/shell and crew-cut spheres to anisotropic pearl-string structures.
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