A high-performance carbon felt electrode for all-vanadium redox flow battery (VRFB) systems is prepared via low-temperature atmospheric pressure plasma treatment in air to improve the hydrophilicity and surface area of bare carbon felt of polyacrylonitrile and increase the contact potential between vanadium ions, so as to reduce the overpotential generated by the electrochemical reaction gap. Brunauer-Emmett-Teller (BET) surface area of the modified carbon felt is, significantly, five times higher than that of the pristine felt. The modified carbon felt exhibits higher energy efficiency (EE) and voltage efficiency (VE) in a single cell VRFB test at the constant current density of 160 mAcm, and also maintains good performance at low temperatures.
View Article and Find Full Text PDFIn this paper, we propose a new, abundant, cost-effective, non-toxic, and environmentally benign iron-copper redox flow battery (Fe/Cu RFB), which employs Fe/Fe and Cu/Cu as the positive and negative electrolytes, respectively. The effect of graphite felt (GF) electrode modification and addition of Bi into the electrolytes on the performance of the Fe/Cu RFB were investigated. It was found that the cell containing Bi in the electrolytes revealed higher coulombic efficiency (89.
View Article and Find Full Text PDFThis work studied the concentration of hydrolyzates obtained from dilute acid hydrolysis of rice straw using nanofiltration (NF). In order to minimize the Donnan exclusion effect of the membrane, the hydrolyzate solution was controlled at low pH value. Negative retentions of both furans and carboxylic acids were observed.
View Article and Find Full Text PDFThe nuclear facilities at Institute of Nuclear Energy Research (INER) had been successively decommissioned and decontaminated over the recent years. Since dismantling was a complex task, to achieve the main goal was minimization of radioactive waste production and required the set-up of procedures, criteria of free release, strict follow-up and traceability at all steps. This study gave an overview of the efforts on non-destructive assay (NDA) of relatively large volumes of waste and the sampling of contaminated waste with radiochemical analysis was utilized to determine the radionuclide vectors.
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