kinetics of the CHNH + NO reaction: formation of nitramines and -alkyl nitroxides.

This study provides a detailed understanding of how the reaction between CHNH, one of the primary products of the CHNH + OH/Cl reactions, and NO occurs in the atmosphere since the reaction is expected to be a dominant sink for the tropospheric CHNH radical. First, we focus on the reaction of the aminyl radical CHNH with NO, complementing the known reaction between CHNH and NO, to provide the overall picture of the CHNH + NO system. The reaction was meticulously examined across the extended range of temperature (298-2000 K) and pressure (0.