Synthesize of an Azo Compound: Investigation its Optical Nonlinear Properties and DFT Study.

In the present work, a diazonium salt is prepared by a diazonium reaction of sulfamerazine in the presence of aqueous hydrochloric acid and sodium nitrate. Structural confirmation of azo compounds synthesize is achieved by mass spectrometry, infrared spectroscopy, and H, C nuclear magnetic resonance. The sample geometry is derived using Density Functional Theory (DFT) and DT-DFT applied to the basis set B3LYPL6-311 + G(d,p).

Safety and efficacy of pimecrolimus versus vehicle for the treatment of atopic dermatitis in adults and paediatric population: a systematic review and meta-analysis.

Unlabelled: Atopic dermatitis remains a widespread problem affecting various populations globally. While numerous treatment options have been employed, pimecrolimus remains a potent and viable option. Recently, there has been increasing interest in comparing the safety and efficacy of pimecrolimus with its vehicle.

Close, but no cigar: an unfortunate case of primary angiitis of the central nervous system.

Unlabelled: Primary angiitis of the central nervous system (PACNS) is an uncommon and misunderstood disease, where little is known regarding its immunopathogenesis and appropriate treatment. Due to the constellation of nonspecific clinical features and imaging findings, PACNS is a diagnostic conundrum for clinicians and can be very difficult to treat.

Case Presentation: A 64-year-old male with a history of prostate cancer presented to the emergency department with expressive aphasia and severe headache.

Investigations of Phytoconstituents, Antioxidant and Anti-Liver Cancer Activities of Saueda monoica Forssk Extracted by Microwave-Assisted Extraction.

Background: Wild edible plants are good sources for bioactive compounds, vitamins, and minerals with various applications. They can play a role in supporting the immune system and are highly beneficial as resources. Suaeda monoica Forssk is a wild edible plant that grows in Iraq and it's biological activities have not yet reported.