Controls on regional sulphate distribution in shallow groundwater in the western Canadian Interior Plains.

Sulphate (SO), predominantly derived from sulphur (S)-bearing glacial sediments distributed widely across the Canadian Interior Plains, contributes to high groundwater salinity and can be detrimental to riparian and dry-land ecosystems, agricultural production, and water use. While previous researchers investigated SO distribution and dynamics in shallow groundwater at local scales (<1500 km), we examine SO occurrence in groundwater at larger scales, and to depths of ∼150 m, considering variations in geology, glacial history, climate, and geochemical and hydrogeological settings in the Canadian province of Alberta. Sulphate concentrations in groundwater vary considerably, with 15 % of 139,130 samples above the 500 mg/L Canadian drinking water aesthetic objective.

High diversity, abundance, and expression of hydrogenases in groundwater.

Hydrogen may be the most important electron donor available in the subsurface. Here we analyse the diversity, abundance and expression of hydrogenases in 5 proteomes, 25 metagenomes, and 265 amplicon datasets of groundwaters with diverse geochemistry. A total of 1545 new [NiFe]-hydrogenase gene sequences were recovered, which considerably increased the number of sequences (1999) in a widely used database.

Hydrogen and dark oxygen drive microbial productivity in diverse groundwater ecosystems.

Around 50% of humankind relies on groundwater as a source of drinking water. Here we investigate the age, geochemistry, and microbiology of 138 groundwater samples from 95 monitoring wells (<250 m depth) located in 14 aquifers in Canada. The geochemistry and microbiology show consistent trends suggesting large-scale aerobic and anaerobic hydrogen, methane, nitrogen, and sulfur cycling carried out by diverse microbial communities.

A geochemical and multi-isotope modeling approach to determine sources and fate of methane in shallow groundwater above unconventional hydrocarbon reservoirs.

Due to increasing concerns over the potential impact of shale gas and coalbed methane (CBM) development on groundwater resources, it has become necessary to develop reliable tools to detect any potential pollution associated with hydrocarbon exploitation from unconventional reservoirs. One of the key concepts for such monitoring approaches is the establishment of a geochemical baseline of the considered groundwater systems. However, the detection of methane is not enough to assess potential impact from CBM and shale gas exploitation since methane in low concentrations has been found to be naturally ubiquitous in many groundwater systems.

Occurrence and origin of methane in groundwater in Alberta (Canada): Gas geochemical and isotopic approaches.

To assess potential future impacts on shallow aquifers by leakage of natural gas from unconventional energy resource development it is essential to establish a reliable baseline. Occurrence of methane in shallow groundwater in Alberta between 2006 and 2014 was assessed and was ubiquitous in 186 sampled monitoring wells. Free and dissolved gas sampling and measurement approaches yielded comparable results with low methane concentrations in shallow groundwater, but in 28 samples from 21 wells methane exceeded 10mg/L in dissolved gas and 300,000 ppmv in free gas.