Silica decorated TiO2 for virus inactivation in drinking water--simple synthesis method and mechanisms of enhanced inactivation kinetics.

A new method of modifying TiO2 photocatalysts with SiO2 is developed in which SiO2 nanoparticles are simply mixed with TiO2 in water under ambient conditions. This method does not require the use of toxic solvents or significant energy input. Although the SiO2 modification slightly reduces hydroxyl free radical production, the composite SiO2-TiO2 nanomaterials have markedly higher photocatalytic inactivation rates for a common surrogate virus, bacteriophage MS2 (up to 270% compared to the unmodified TiO2), due to the greatly improved adsorptive density and dark inactivation of MS2.

3D nanoporous nanowire current collectors for thin film microbatteries.

Conventional thin film batteries are fabricated based on planar current collector designs where the high contact resistance between the current collector and electrodes impedes overall battery performance. Hence, current collectors based on 3D architectures and nanoscale roughness has been proposed to dramatically increase the electrode-current collector surface contact areas and hence significantly reduce interfacial resistance. The nanorod-based current collector configuration is one of several 3D designs which has shown high potential for the development of high energy and high power microbatteries in this regard.

Simple route to enhanced photocatalytic activity of p25 titanium dioxide nanoparticles by silica addition.

Silica doped TiO2(P25) nanoparticles are tested for its photocatalytic activity in the degradation of bacteriophage MS2. During our studies it was found that treatment of TiO2(P25) in the glass flasks sealed with silicone grease resulted in a significant improvement in the catalytic activity of the titania. Further improvement can be made by the purposeful reaction of TiO2(P25) with 2.