An Alloy Engineering Strategy toward Helical Microstructures of Achiral π-Conjugated Molecules for Circularly Polarized Luminescence.

Helical assembly has been demonstrated to efficiently facilitate the circularly polarized luminescence (CPL) performances, but the synthesis of micro- and nanohelices from rigid achiral π-conjugated compounds remains challenging due to the absence of bilayer structures or complementary hydrogen-bonding interactions. Here, we develop an alloying strategy for the realization of helical microstructures from achiral anthracene/anthracene derivatives with -/-axis modification or anthracene/tetracene derivatives with -/-axis modification via solution coassembly. Interestingly, two anthracene derivatives bearing asymmetric phenyl/phenylethynyl groups and symmetric phenylethynyl groups can assemble into spiral microribbons with a fractal branching pattern.