Microaerobic condition as pretreatment for improving anaerobic digestion: A review.

Pretreatment of waste before anaerobic digestion (AD) has been extensively studied during the last decades. One of the biological pretreatments studied is the microaeration. This review examines this process, including parameters and applications to different substrates at the lab, pilot and industrial scales, to guide further improvement in large-scale applications.

Sulfur-based mixotrophic denitrification with the stoichiometric S/N ratio and methanol supplementation: effect of the C/N ratio on the process.

The impact of the organic carbon to nitrate ratio (C/N ratio) on mixotrophic denitrification rate has been scarcely studied. Thus, this work aims to investigate the effect of the C/N ratio on the mixotrophic denitrification when methanol is used as a source of organic matter and elemental sulfur as an electron donor for autotrophic denitrification. For this, two initial concentrations of NO-N (50 and 25 mg/L) at a stoichiometric ratio of S/N, and four initial C/N ratios (0, 0.

Valorization of oat husk by hydrothermal carbonization: Optimization of process parameters and anaerobic digestion of spent liquors.

The hydrothermal carbonization (HTC) optimization of oat husk was performed using a response surface methodology. Furthermore, anaerobic digestion (AD) of spent liquor and hydrochar addition were evaluated in the biomethane potential (BMP) test. Results found that temperature influences the most in the studied responses (i.

Modeling of the effect of zeolite concentration on the biological nitrification process in the presence of sulfide and organic matter.

The evaluation of the nitrification kinetics in the simultaneous presence of sulfide and organic matter using zeolite as improver was the main goal of this work. According to the sensitivity and collinearity analyses, five parameters were the most sensitive in the model, whose calibrated values were: = 0.02642 ± 0.

Valorization of the liquid fraction of co-hydrothermal carbonization of mixed biomass by anaerobic digestion: Effect of the substrate to inoculum ratio and hydrochar addition.

The effect of the substrate to inoculum ratio (SIR) on the anaerobic digestion (AD) of the liquid fractions (LFs) of co-hydrothermally treated mixed biomass (sewage sludge (SS) and the organic fraction of municipal solid waste (MSW)) was evaluated. The impact of SS + MSW-hydrochar was also studied at different hydrochar concentrations (0, 1, 5, 10, 15, 20 and 25 g/L), in two of the LFs studied. The SIR had a significant impact on methane yield (YCH) and organic matter degradation, with low methane production (4-44 NmLCH/g tCOD) observed for all LFs at SIR = 1:3.

Fly ash as stimulant for anaerobic digestion: effect over hydrolytic stage and methane generation rate.

Thermoelectric fly ash was used as a micronutrient source for microorganisms in the anaerobic digestion process of thermally pretreated (1 hour, 120 °C) secondary sludge. The obtained results not only suggest that fly ash improves methane generation in the conversion of volatile fatty acids into methane, but also show a new observation, that the fly ash contributes in the particulate organic solubilization. The maximum methane production rate increased from 6.

Anaerobic digestion of wastewater rich in sulfate and sulfide: effects of metallic waste addition and micro-aeration on process performance and methane production.

This work explores the effect of two metallic wastes (mining wastes, MW; fly ashes, FA) and micro-aeration (MA) on the anaerobic digestion of wastewater which is rich in sulfate and sulfide. Two initial COD concentrations (5,000 and 10,000 mg/L) were studied under both conditions in batch systems at 35 °C, with a fixed COD/SO ratio = 10, with 100 mg/L of S. It was observed that the use of MW and FA in the assays with an initial COD concentration of 10,000 mg/L resulted in a simultaneous increase in COD removal, sulfate removal, sulfide removal and methane generation, while MA only improved the COD and sulfide removals in comparison with the control system.

Degradation of ampicillin antibiotic by electrochemical processes: evaluation of antimicrobial activity of treated water.

Ampicillin (AMP) is an antibiotic widely used in hospitals and veterinary clinics around the world for treating infections caused by bacteria. Therefore, it is common to find traces of this antibiotic in wastewater from these entities. In this work, we studied the mineralization of this antibiotic in solution as well as the elimination of its antimicrobial activity by comparing different electrochemical advanced oxidation processes (EAOPs), namely electro-oxidation with hydrogen peroxide (EO-HO), electro-Fenton (EF), and photo electro-Fenton (PEF).

Effective removal of the antibiotic Nafcillin from water by combining the Photoelectro-Fenton process and Anaerobic Biological Digestion.

The elimination of the antibiotic Nafcillin (NAF), which is usually used in hospitals and veterinary clinics around the world, was assessed through a combination of three advanced electrochemical oxidation processes followed by anaerobic digestion process. In the first stage different electrochemical advanced oxidation processes (EAOPs) were used: electro-oxidation with hydrogen peroxide (EO-HO), electro-Fenton (EF) and Photo electro-Fenton (PEF). After PEF, almost complete and highly efficient degradation and elimination of NAF was achieved, with the concomitant elimination of the associated antimicrobial activity.

A new model for including the effect of fly ash on biochemical methane potential.

The modelling of the effect of trace elements on anaerobic digestion, and specifically the effect of fly ash, has been scarcely studied. Thus, the present work was aimed at the development of a new function that allows accumulated methane models to predict the effect of FA on the volume of methane accumulation. For this, purpose five fly ash concentrations (10, 25, 50, 250 and 500mg/L) using raw and pre-treated sewage sludge were used to calibrate the new function, while three fly ash concentrations were used (40, 150 and 350mg/L) for validation.

Biochemical methane potential from sewage sludge: Effect of an aerobic pretreatment and fly ash addition as source of trace elements.

The effect of aerobic pretreatment and fly ash addition on the production of methane from mixed sludge is studied. Three assays with pretreated and not pretreated mixed sludge in the presence of fly ash (concentrations of 0, 10, 25, 50, 250 and 500mg/L) were run at mesophilic condition. It was found that the combined use of aerobic pretreatment and fly ash addition increases methane production up to 70% when the fly ash concentrations were lower than 50mg/L, while concentrations higher than 250mg/L cause up to 11% decrease of methane production.

Performance evaluation of micro-aerobic hydrolysis of mixed sludge: Optimum aeration and effect on its biochemical methane potential.

This study evaluated the performance of a micro-aerobic hydrolysis of mixed sludge and its influence as a pretreatment of this waste for its subsequent anaerobic digestion. Three experimental series were carried out to evaluate the optimum micro-aeration levels in the range from 0.1 to 0.

Autotrophic and heterotrophic denitrification for simultaneous removal of nitrogen, sulfur and organic matter.

The aim of this investigation was to assess the startup and operation of a laboratory-scale hybrid UASB-Anaerobic Filter Reactor (UASFB) of 1 L volume, kept at 30°C, in order to carry out a simultaneous autotrophic and heterotrophic denitrification process. First, the heterotrophic and autotrophic populations were separately enriched, with specific cultures and subsequently the UASFB was inoculated with 2 g L(-1) of volatile suspended solids (VSS), with a ratio of 1.5:1 (autotrophs: heterotrophs).

Biodegradability and methane production from secondary paper and pulp sludge: effect of fly ash and modeling.

The effect of fly ash on biodegradability and methane production from secondary paper and pulp sludge, including its modeling, was evaluated. Three tests with fly ash concentrations of 0, 10 and 20 mg/L were evaluated at 32 °C. Methane production was modeled using the modified Gompertz equation.

Simultaneous effect of initial moisture content and airflow rate on biodrying of sewage sludge.

The simultaneous effect of initial moisture content (initial Mc) and air-flow rate (AFR) on biodrying performance was evaluated. For the study, a 3(2) factorial design, whose factors were AFR (1, 2 and 3 L/min kg(TS)) and initial Mc (59, 68 and 78% w.b.

Biodrying of sewage sludge: kinetics of volatile solids degradation under different initial moisture contents and air-flow rates.

This study focuses on the kinetics of the biodegradation of volatile solids (VS) of sewage sludge for biodrying under different initial moisture contents (Mc) and air-flow rates (AFR). For the study, a 3(2) factorial design, whose factors were AFR (1, 2 or 3L/minkgTS) and initial Mc (59%, 68% and 78% w.b.

Biodrying of pulp and paper secondary sludge: kinetics of volatile solids biodegradation.

This study focuses on the kinetics of volatile solids (VS) biodegradation of the biodrying process using pulp and paper secondary sludge. The experiments were carried out with air-flow rates of 0.51, 1.

Simultaneous C and N removal from saline salmon effluents in filter reactors comprising anoxic-anaerobic-aerobic processes: effect of recycle ratio.

Salmon processing generates saline effluents with high protein load. To treat these effluents, three compact tubular filter reactors were installed and an integrated anoxic/anaerobic/aerobic process was developed with recycling flow from the reactor's exit to the inlet stream in order to save organic matter (OM) for denitrification. The reactors were aerated in the upper section with recycle ratios (RR) of 0, 2, and 10, respectively, at 30°C.

Behavior of the anaerobic treatment of tannery wastewater at different initial pH values and sulfate concentrations.

The influence of initial pH and sulfate concentration on the anaerobic digestion of tannery wastewater was studied using the specific methanogenic activity (SMA) test. The SMA tests were performed with a chemical oxygen demand (COD) concentration of 6.5 g/L and SO(-2)4 concentrations of 1.

Modeling of an anoxic/methanogenic biofilm: effect of pH calculation within the biofilm.

The models of anoxic/methanogenic processes in biofilm reactors published until now have supposed that pH does not change between the bulk liquid and biofilm. These assumptions are not necessarily valid for processes in reactors with biofilms. The present work studied an anoxic/methanogenic biofilm reactor incorporating the pH variation in both bulk and biofilm.

Modeling of simultaneous denitrification--anaerobic digestion--organic matter aerobic oxidation and nitrification in an anoxic-anaerobic-aerobic compact filter reactor.

A mathematical model was developed for a compact anoxic-anaerobic-aerobic filter reactor with liquid recirculation for the treatment of fishing effluents. The model includes denitrification, anaerobic digestion, aerobic carbon oxidation and nitrification steps, as well as an evaluation of the liquid gas mass transfer and pH. The model was calibrated using one experimental condition at a recycling ratio (R)=10, and was validated with R equal to 2 and 0, with an organic concentration of 554±24 mg TOCL(-1), salinity of 24 g L(-1) and hydraulic retention time (HRT) of 2 d.

Modeling of the denitrification/anaerobic digestion process of salmon fishery wastewater in a biofilm tubular reactor.

The literature has paid scarce attention to the modeling of the denitrification-anaerobic digestion process in packed bed biofilm tubular reactors used to treat wastewater. The present study obtained a steady-state model for industrial salmon fishery wastewater treatment in a biofilm tubular reactor, including pH as a variable and the effect of biomass on hydrolysis. The axial profile of the reactor components and process efficiency were predicted with deviations below 6%.