Platinum-Tellurium Heterojunction Nanosheet Assemblies for Efficient Direct Formic Acid Electrooxidation Catalysis.

Two-dimensional (2D) heterojunction nanomaterials offer exceptional physicochemical and catalytic properties, thanks to their special spatial electronic structure. However, synthesizing morphologically uniform 2D platinum (Pt)-based metallic nanomaterials with diverse crystalline phases remains a formidable challenge. In this study, we have achieved the successful synthesis of advanced 2D platinum-tellurium heterojunction nanosheet assemblies (Pt-PtTe HJNSAs, = 0, 1, 2), seamlessly integrating both trigonal PtTe (-PtTe) and cubic Pt (-Pt) phases.

Structure and Defect Engineering of VSSe Quantum Dots Confined in a Nitrogen-Doped Carbon Framework for High-Performance Sodium-Ion Storage.

Constructing quantum dot-scale metal sulfides with defects and strongly coupled with carbon is significant for advanced sodium-ion batteries (SIBs). Herein, Se substituted VS quantum dots with anionic defects confined in nitrogen-doped carbon matrix (VSSe/NC) are fabricated. Introducing element Se into VS crystal expands the interlayer distance of VS, and triggers anionic defects, which can facilitate Na diffusions and act as active sites for Na storage.

Preparation of high strength, self-healing conductive hydrogel based on polysaccharide and its application in sensor.

The development of cost-effective, eco-friendly conductive hydrogels with excellent mechanical properties, self-healing capabilities, and non-toxicity holds immense significance in the realm of biosensors. The biosensors demonstrate promising applications in the fields of biomedical engineering and human motion detection. A unique double-network hydrogel was prepared through physical-chemical crosslinking using chitosan (CS), polyacrylic acid (AA), and sodium alginate (SA) as raw materials.

The mechanistic basis for the effects of electroacupuncture on neuropathic pain within the central nervous system.

Nociceptive signaling responses to painful stimuli are transmitted to the central nervous system (CNS) from the afferent nerves of the periphery through a series of neurotransmitters and associated signaling mechanisms. Electroacupuncture (EA) is a pain management strategy that is widely used, with clinical evidence suggesting that a frequency of 2-10 Hz is better able to suppress neuropathic pain in comparison to higher frequencies such as 100 Hz. While EA is widely recognized as a viable approach to alleviating neuralgia, the mechanistic basis underlying such analgesic activity remains poorly understood.

[Discussion on the safety of acupuncture in experimental animals].

Many basic studies on acupuncture need to be carried out on experimental animals. However, the safety of acupuncture in experimental animals has been neglected for a long time. In the present paper, we make a discussion on the current situations, causes, its influence on research results and countermeasures of acupuncture safety events in experimental animals, so as to promote the safety evaluation of acupuncture in experimental animals and the standardized operation of acupuncture.

Interventional Occlusion of Large Patent Ductus Arteriosus in Adults with Severe Pulmonary Hypertension.

(1) Background: the indications for transcatheter closure of large patent ductus arteriosus (PDA) with severe pulmonary hypertension (PH) are still unclear, and scholars have not fully elucidated the factors that affect PH prognosis. (2) Methods: we retrospectively enrolled 134 consecutive patients with a PDA diameter ≥10 mm or a ratio of PDA and aortic >0.5.

Carbon Nanomaterials-Based Electrochemical Sensors for Heavy Metal Detection.

Heavy metals are commonly found in a wide range of environmental settings metals, but the potential toxicity associated with heavy metal exposure represents a major threat to global public health. It is thus vital that approaches to efficiently, reliably, and effectively detecting heavy metals in a range of sample types be established. Carbon nanomaterials offer many advantageous properties that make them well-suited to the design of sensitive, selective, easy-to-operate electrochemical biosensors ideal for detecting heavy metal ions.

Chemical Transformation Induced Core-Shell NiP@FeP Heterostructures toward Efficient Electrocatalytic Oxygen Evolution.

The oxygen evolution reaction (OER) is a crucial reaction in water splitting, metal-air batteries, and other electrochemical conversion technologies. Rationally designed catalysts with rich active sites and high intrinsic activity have been considered as a hopeful strategy to address the sluggish kinetics for OER. However, constructing such active sites in non-noble catalysts still faces grand challenges.

Transcatheter closure of inferior sinus venosus defect using a patent ductus arteriosus occluder following simulation with a 3D-printed model.

Background: Transcatheter closure of inferior sinus venosus defect (ISVD) is still contraindication. To explore whether transcatheter closure with patent ductus arteriosus (PDA) occluders is possible for ISVD.

Methods: From June 2014 to March 2021, 12 patients were recruited diagnosed as <25 mm ISVD.

Construction of Core-Shell CoMoO@γ-FeOOH Nanosheets for Efficient Oxygen Evolution Reaction.

The oxygen evolution reaction (OER) occurs at the anode in numerous electrochemical reactions and plays an important role due to the nature of proton-coupled electron transfer. However, the high voltage requirement and low stability of the OER dramatically limits the total energy converting efficiency. Recently, electrocatalysts based on multi-metal oxyhydroxides have been reported as excellent substitutes for commercial noble metal catalysts due to their outstanding OER activities.

Transcatheter Closure of Patent Ductus Arteriosus via Different Approaches.

There have been marked advances in devices such as Amplatzer Duct Occluder II (ADO-II) or vascular plug through 5Fr delivery sheath for closure of patent ductus arteriosus (PDA) in the past five decades, making it possible for cardiologists to deliver occluders via different approaches. However, comparisons of these different approaches have not been reported. Therefore, the aim of this study was to summarize and compare the advantages of different approaches for PDA closure, and to guide clinical strategies.

Carbon-Based Electrochemical Sensors for and Neurotransmitter Detection.

As essential neurological chemical messengers, neurotransmitters play an integral role in the maintenance of normal mammalian physiology. Aberrant neurotransmitter activity is associated with a range of neurological conditions including Parkinson's disease, Alzheimer's disease, and Huntington's disease. Many studies to date have tested different approaches to detecting neurotransmitters, yet the detection of these materials within the brain, due to the complex environment of the brain and the rapid metabolism of neurotransmitters, remains challenging and an area of active research.

Combination of F-ASO and Targeted Medical Therapy in Patients With Secundum ASD and Severe PAH.

Objectives: This study was conducted to investigate the combined use of fenestrated atrial septal occluder (F-ASO) and targeted medical therapy (TMT) in patients with secundum atrial septal defect (ASD) and severe pulmonary arterial hypertension (PAH).

Background: Treatment of patients with ASD and severe PAH is still challenging.

Methods: After ethical approval was obtained, 56 consecutive patients with ASD with severe PAH were included (7 men, 49 women; median age 50.

Facile synthesis of CoFeP microcubes derived from metal-organic frameworks for efficient oxygen evolution reaction.

The electrochemical splitting of water provides an attractive method for the production of hydrogen fuels. Unfortunately, the slow kinetics of oxygen evolution (OER) on the anode side of the electrolyzer hinders the efficient and large-scale hydrogen production. In this study, starting from metal-organic frameworks (MOFs), a series of bimetal phosphides CoFeP (x = 0.

Off-label use of duct occluder in transcatheter closure of secundum atrial septal defect with no rim to right pulmonary vein.

Objective: Transcatheter closure is usually contraindicated in secundum atrial septal defect with no rim to right pulmonary vein. The morphology of an atrial septal defect is special in these patients, and the off-label use of a duct occluder might make transcatheter closure possible with the assistance of a personalized heart model. However, the related data are absent.

Three-dimensional printing assisted transcatheter closure of atrial septal defect with deficient posterior-inferior rim.

Objective: Though successful transcatheter closure has been reported in secundum atrial septal defect (ASD) with deficient posterior-inferior rim, it is still difficult to screen the appropriate candidates. Three-dimensional printing (3DP) makes in vitro trial occlusion possible, and might provide a feasible method in the prediction of successful closure.

Methods: Thirty-five consecutive ASD patients (10M/25F, age, 47.

Structure-Designed Synthesis of CoP Microcubes from Metal-Organic Frameworks with Enhanced Supercapacitor Properties.

Metal-organic framework-based supercapacitors have been widely recognized as the best energy storage devices for future portable electronic equipment. Herein, CoP- T ( T = 300, 350, and 400 °C) microcubes with a solid and hollow microstructure were successfully synthesized by low-temperature phosphorization of [CHNH][Co(HCOO)] precursor at desired temperatures. The morphology, structure, and composition of the prepared CoP-350 °C samples were analyzed by scanning electron microscopy, transmission electron microscopy, and X-ray photoelectron spectroscopy.

Co/Cu-MFF derived mesoporous ternary metal oxide microcubes for enhancing the catalytic activity of the CO oxidation reaction.

Metal-organic framework (MOF)-based derivatives with uniform micro/mesoporous structures have attracted a great deal of interest in various research fields. Herein, we report a simple strategy to design functional mesoporous ternary metal oxides with controlled composition through direct pyrolysis of Co/Cu bimetal-formate frameworks (Co/Cu-MFFs), which were prepared by a facile one-step liquid-phase precipitation method, exhibiting uniform distribution of two different metal species and good structural integrity. The obtained mesoporous ternary metal oxide Cu Co O ( = 0.

Congenital atresia of the left main coronary artery with noncompaction of the ventricular myocardium in an asymptomatic young child.

Congenital atresia of the left main coronary artery (LMCA) is an extremely rare cardiac anomaly, and no cases have been reported from the mainland of China. The diagnosis for the 20-month-old boy in the reported case highlights the essentiality of comprehensive diagnostic measures. To avoid a misdiagnosis, electrocardiographic and echocardiographic evidence should be vigilantly explored in young children suspected of having dilated cardiomyopathy.

[Value of cardiac CT examination in middle-aged and elderly patients with atrial septal defect before planned transcatheter closure].

Objective: To investigate the value of the cardiac CT examination for decision making in middle-aged and elderly patients before planned transcatheter atrial septal defect (ASD) closure.

Methods: Cardiac CT was performed in 63 adult patients [18 males, aged from 50 to 77 years, mean age (56.87 ± 5.

Patients with metabolic syndrome have prolonged corrected QT interval (QTc).

Background: Prolongation of corrected QT interval (QTc) increases morbidity and mortality and QTc has been found to be longer in patients with diabetes mellitus than in healthy controls. It is still inconclusive whether the metabolic syndrome results in QTc prolongation.

Hypothesis: We hypothesized that metabolic syndrome might contribute to risk of QTc prolongation.

Contemporary analysis of predictors and etiology of ventricular fibrillation during diagnostic coronary angiography.

Objectives: To assess the incidence, investigate the predictors and analyze the causes of ventricular fibrillation (VF) during coronary angiography (CA) on the condition of current techniques.

Methods: From April 2004 to January 2007, a total 22,254 patients (27,798 procedures) received CA procedures in our center; 27 patients developed VF during CA. This report was to retrospectively analyze the clinical basic characteristics, coronary angiographic characteristics and CA procedure records of these patients.