Stimulus-Responsive Lanthanide MOF Materials Encapsulated with Viologen Derivatives: Characterization, Photophysical Properties and Sensing on Nitrophenols.

Viologens (1,1'-disubstituted 4,4'-bipyridyls) possessing electron-deficient properties and redox activity are a class of suitable chromophores to assemble metal-organic hybrid photochromic materials. Thus, viologen-functionalized metal-organic frameworks (MOFs) have attracted much attention for their photochromic properties; however, the syntheses of lanthanide-viologen hybrid crystalline photochromic materials still face many challenges. For example, the structures and properties of the final products are difficult to predict and are limited by molecular configurations.

Transport of self-propelled particles across a porous medium: trapping, clogging, and the Matthew effect.

We study the transport of self-propelled particles from one free chamber to another across two stripe-like areas of dense porous medium. The medium is mimicked by arrays of obstacles. We find that active motion could greatly speed up the transport of particles.

Microrotor of a chain-grafted colloidal disk immersed in the active bath: The impact of particle concentration, grafting density, and chain rigidity.

In an earlier work, we discussed the possibility to realize a microrotor by immersing a chain-grafted colloidal disk in a thin film of active-particle suspension. Under certain conditions, the colloidal disk rotates unidirectionally driven by the bath active particles. Here we systematically study the role of active-particle concentration, grafting density, and chain rigidity in the phenomenon of the spontaneous symmetry breaking of the chain configurations and the unidirectional rotation of the disk.

Spontaneous symmetry breaking induced unidirectional rotation of a chain-grafted colloidal particle in the active bath.

Exploiting the energy of randomly moving active agents such as bacteria is a fascinating way to power a microdevice. Here we show, by simulations, that a chain-grafted disk-like colloidal particle can rotate unidirectionally and hence output work when immersed in a thin film of active particle suspension. The collective spontaneous symmetry breaking of chain configurations is the origin of the unidirectional rotation.

The unique role of bond length in the glassy dynamics of colloidal polymers.

Bond length is generally not considered as a controllable variable for molecular polymers. Hence, no experimental, simulation or theoretical research, to our knowledge, has examined the influence of bond length on the glassy dynamics of polymers. Recently, a new class of assembling materials called "colloidal polymers" has been synthesized.

Glassy dynamics of model colloidal polymers: The effect of "monomer" size.

In recent years, attempts have been made to assemble colloidal particles into chains, which are termed "colloidal polymers." An apparent difference between molecular and colloidal polymers is the "monomer" size. Here, we propose a model to represent the variation from molecular polymer to colloidal polymer and study the quantitative differences in their glassy dynamics.

A New Self-Consistent Field Model of Polymer/Nanoparticle Mixture.

Field-theoretical method is efficient in predicting assembling structures of polymeric systems. However, it's challenging to generalize this method to study the polymer/nanoparticle mixture due to its multi-scale nature. Here, we develop a new field-based model which unifies the nanoparticle description with the polymer field within the self-consistent field theory.

Brush in the bath of active particles: Anomalous stretching of chains and distribution of particles.

The interaction between polymer brush and colloidal particles has been intensively studied in the last two decades. Here, we consider a flat chain-grafted substrate immersed in a bath of active particles. Simulations show that an increase in the self-propelling force causes an increase in the number of particles that penetrate into the brush.

Theory of activated dynamics and glass transition of hard colloids in two dimensions.

The microscopic nonlinear Langevin equation theory is applied to study the localization and activated hopping of two-dimensional hard disks in the deeply supercooled and glass states. Quantitative comparisons of dynamic characteristic length scales, barrier, and their dependence on the reduced packing fraction are presented between hard-disk and hard-sphere suspensions. The dynamic barrier of hard disks emerges at higher absolute and reduced packing fractions and correspondingly, the crossover size of the dynamic cage which correlates to the Lindemann length for melting is smaller.