Stochastic accretion of the Earth.

Chondritic meteorites are thought to be representative of the material that formed the Earth. However, the Earth is depleted in volatile elements in a manner unlike that in any chondrite, and yet these elements retain chondritic isotope ratios. Here we use N-body simulations to show that the Earth did not form from chondrites, but rather by stochastic accretion of many precursor bodies whose variable compositions reflect the temperatures at which they formed.

Fractional crystallisation of eclogite during the birth of a Hawaiian Volcano.

The initial melts erupted by a Hawaiian volcano have a range of alkalic compositions but are rarely observed as they are covered by enormous volumes of shield stage tholeiites. A remarkable record of the early evolution of Hawaiian volcanoes, however, is preserved by a volcanic sandstone dredged from the submarine flank of Kilauea, which contains a suite of petrogenetically related pre-shield basanite to nephelinite glasses. Here we show that the systematic variation in the rare earth element (REE) patterns of these samples requires the fractional crystallisation of garnet.

Redox state of Earth's magma ocean and its Venus-like early atmosphere.

Exchange between a magma ocean and vapor produced Earth's earliest atmosphere. Its speciation depends on the oxygen fugacity (O) set by the Fe/Fe ratio of the magma ocean at its surface. Here, we establish the relationship between O and Fe/Fe in quenched liquids of silicate Earth-like composition at 2173 K and 1 bar.

Mineral Surface Rearrangement at High Temperatures: Implications for Extraterrestrial Mineral Grain Reactivity.

Mineral surfaces play a critical role in the solar nebula as a catalytic surface for chemical reactions and potentially acted as a source of water during Earth's accretion by the adsorption of water molecules to the surface of interplanetary dust particles. However, nothing is known about how mineral surfaces respond to short-lived thermal fluctuations that are below the melting temperature of the mineral. Here we show that mineral surfaces react and rearrange within minutes to changes in their local environment despite being far below their melting temperature.

The global pattern of trace-element distributions in ocean floor basalts.

The magmatic layers of the oceanic crust are created at constructive plate margins by partial melting of the mantle as it wells up. The chemistry of ocean floor basalts, the most accessible product of this magmatism, is studied for the insights it yields into the compositional heterogeneity of the mantle and its thermal structure. However, before eruption, parental magma compositions are modified at crustal pressures by a process that has usually been assumed to be fractional crystallization.

Evidence against a chondritic Earth.

The (142)Nd/(144)Nd ratio of the Earth is greater than the solar ratio as inferred from chondritic meteorites, which challenges a fundamental assumption of modern geochemistry--that the composition of the silicate Earth is 'chondritic', meaning that it has refractory element ratios identical to those found in chondrites. The popular explanation for this and other paradoxes of mantle geochemistry, a hidden layer deep in the mantle enriched in incompatible elements, is inconsistent with the heat flux carried by mantle plumes. Either the matter from which the Earth formed was not chondritic, or the Earth has lost matter by collisional erosion in the later stages of planet formation.

Collisional erosion and the non-chondritic composition of the terrestrial planets.

The compositional variations among the chondrites inform us about cosmochemical fractionation processes during condensation and aggregation of solid matter from the solar nebula. These fractionations include: (i) variable Mg-Si-RLE ratios (RLE: refractory lithophile element), (ii) depletions in elements more volatile than Mg, (iii) a cosmochemical metal-silicate fractionation, and (iv) variations in oxidation state. Moon- to Mars-sized planetary bodies, formed by rapid accretion of chondrite-like planetesimals in local feeding zones within 106 years, may exhibit some of these chemical variations.

A furnace design for XANES spectroscopy of silicate melts under controlled oxygen fugacities and temperatures to 1773 K.

A controlled-atmosphere furnace has been constructed for X-ray absorption spectroscopy experiments under imposed oxygen fugacities at temperatures up to 1773 K. The use of the furnace is demonstrated in a study of the oxidation state of Cr in a basaltic silicate melt (mid-ocean ridge basalt) by K-edge XANES spectroscopy. This is the first time the Cr(2+)/Cr(3+) ratio has been identified directly in an Fe-bearing melt.