Modification of the Se/MoO Rear Interface for Efficient Wide-Band-Gap Trigonal Selenium Solar Cells.

Trigonal selenium (t-Se) is a promising wide-band-gap photovoltaic material with a high absorption coefficient, abundant resources, simple composition, nontoxicity, and a low melting point, making it suitable for absorbers in advanced indoor and tandem photovoltaic applications. However, severe electrical losses at the rear interface of the t-Se absorber, caused by work function and lattice mismatches, limit the voltage output and overall performance. In this study, a strategy to enhance carrier transport and collection by modifying interfacial chemical interactions is proposed.

Plant-Based Bimetallic Silver-Zinc Oxide Nanoparticles: A Comprehensive Perspective of Synthesis, Biomedical Applications, and Future Trends.

The universal emphasis on the study of green nanotechnology has led to biologically harmless uses of wide-ranged nanomaterials. Nanotechnology deals with the production of nanosized particles with regular morphology and properties. Various researches have been directed on nanomaterial synthesis by physical, chemical, and biological means.

Comprehensive transcriptome and metabolome profiling reveal metabolic mechanisms of Nitraria sibirica Pall. to salt stress.

Nitraria sibirica Pall., a typical halophyte that can survive under extreme drought conditions and in saline-alkali environments, exhibits strong salt tolerance and environmental adaptability. Understanding the mechanism of molecular and physiological metabolic response to salt stress of plant will better promote the cultivation and use of halophytes.

Tissue tolerance mechanisms conferring salinity tolerance in a halophytic perennial species Nitraria sibirica Pall.

Plant salt tolerance relies on a coordinated functioning of different tissues and organs. Salinity tissue tolerance is one of the key traits that confer plant adaptation to saline environment. This trait implies maintenance low cytosolic Na+/K+ ratio in metabolically active cellular compartments.

A dual-response ratiometric fluorescent probe for hypochlorite and hydrazine detection and its imaging in living cells.

In this work, a dual-response ratiometric fluorescent probe (E)-3-(5-(2-nitrovinyl)thiophen-2-yl)-9-phenyl-9H-carbazole (NTPC) for high selectivity and sensitivity detection of ClO and NH was successfully developed. This probe NTPC showed ratiometric fluorescent response to ClO and NH, which induces obvious naked-eye color changes, respectively. In addition, the NTPC for ClO and NH detection displayed low detection limits of 71.

Two novel polysaccharides from Solanum nigrum L. exert potential prebiotic effects in an in vitro fermentation model.

In this research, two novel polysaccharides (S1 and S2) from Solanum nigrum L were extracted and purified. Then homogeneity, molecular weights, major chemical contents and monosaccharide compositions of S1 and S2 were determined. Then, the effects of S1 and S2 on human faecal microbial community and short-chain fatty acid production were investigated using an in vitro fermentation model.

Tailoring the Vertical Morphology of Organic Films for Efficient Planar-Si/Organic Hybrid Solar Cells by Facile Nonpolar Solvent Treatment.

The optical and electrical properties of the blending organic film poly(3,4-ethylenedioxy-thiophene):poly(styrenesulfonate) (PEDOT:PSS) are strongly affected by its morphology, resulting in the performance variation in Si/organic hybrid solar cells. Here, a facile postsolvent treatment is used to tailor the vertical morphology of PEDOT:PSS by introducing a nonpolar solvent. X-ray photoelectron spectroscopy depth-profiling measurements show that the distribution of PEDOT and PSS on the surface of n-type Si can be changed by nonpolar solvent -hexane (NHX) treatment, where more PSS aggregate at the bottom of the blend film and more PEDOT float up to the top, as compared with the reference sample.

Degradation mechanism, intermediates and toxicology assessment of tris-(2-chloroisopropyl) phosphate using ultraviolet activated hydrogen peroxide.

Organophosphate flame retardants (OPFRs), one kind of emerging flame retardants, have received prevalent attention owing to their ubiquity in aquatic matrices and their characteristics of being refractory to biodegradation. In current research, the degradation mechanism of tris-(2-chloroisopropyl) phosphate (TCPP), one of OPFRs, and its toxicological evaluation using UV-driven hydroxyl radical oxidation were investigated. A pseudo-first order reaction was fitted with an apparent rate constant (K) of 0.

Palladium-Catalyzed -Stereocontrolled Ring Opening of Oxabicyclic Alkenes with Arylsulfonyl Hydrazides.

A novel palladium-catalyzed ring-opening reaction of oxabicyclic alkenes with arylsulfonyl hydrazides was first developed. In this work, we provide an efficient one-pot reaction to afford the corresponding 2-aryl-1,2-dihydronaphthalen-1-ols and 2-aryl-naphthalenes in moderate to excellent yields (up to 95%) under an open-air condition. Various types of functional groups attached to the substrates were tolerated well in this method.

Three-Component Cycloaddition To Synthesize Aziridines and 1,2,3-Triazolines.

An efficient three-component cycloaddition of oxa(aza)bicyclic alkenes/norbornene in the presence of NaN and arylsulfonyl chlorides was developed, affording the corresponding aziridine products in good yields (up to 82%) with moderate to good / selectivities (up to >99:1 /). Further studies showed that the cycloaddition of oxa(aza)bicyclic alkenes in the presence of NaN and chloroalkanes could afford the -cycloadduct 1,2,3-triazolines in good to excellent yields (up to 95%). Compared with the existing methodologies, the current protocol demands very simple and mild reaction conditions and is a metal-free catalyzed reaction.

Controllable Cs FAPbI Single-Crystal Morphology via Rationally Regulating the Diffusion and Collision of Micelles toward High-Performance Photon Detectors.

Cs FAPbI single crystals are expected to provide more excitement in optoelectronic applications, including photodetector, laser, light-emitting diode, etc. Herein, we aim to gain an in-depth understanding of the growth mechanisms of perovskite single crystal with various morphologies in view of microscopic dynamics by the combination of component, structure, and solvent engineering. A sequence of Cs FAPbI (0 ≤ x ≤ 0.

Spatial-temporal distribution of phthalate esters from riverine outlets of Pearl River Delta in China.

The aquatic environments of the Pearl River Delta (PRD) in China have been contaminated by various industrial chemicals from local industries. In this study, the spatial-temporal distribution of six priority phthalate esters (PAEs) in surface water and sediments from the PRD was investigated. The PAEs were detected with total concentrations (Σ6PAEs) ranging from 0.

Novel mixed-valent Co(II)₂Co(III)₄Ln(III)₄ aggregates with ligands derived from tris-(hydroxymethyl)aminomethane (Tris).

Isostructural Co(II)₂Co(III)₄Ln(III)₄ (Ln = Y (1), Gd (2) and Dy (3)) coordination clusters formed using the ligand Tris are the first examples of 3d-4f complexes involving this ligand and show weak ferromagnetic coupling between the Co(II) ions and slow relaxation (SMM) behaviour for 3.

Construction of two 3D homochiral frameworks with 1D chiral pores via chiral recognition.

The reactions of a pair of enantiomers of macrocyclic nickel(II) complexes with racemic penicillamine generated two 3D hydrogen-bonded homochiral frameworks of {[Ni(f-(SS)-L)](2)(l-pends)(ClO(4))(2)}(n) (Λ-1) and {[Ni(f-(RR)-L)](2)(d-pends) (ClO(4))(2)}(n) (Δ-1). The frameworks possess 1D tubular pores and opposite right/left-handed helical porous surfaces (L = 5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane; pends(2-) = penicillaminedisulfide anion).

[FTIR studies of L-threonic acid and its metal compounds].

Highly pure solid compounds, such as L-threonic acid, calcium L-threonate, magnesium L-threonate, manganese L-threonate, cobalt L-threonate, nickel L-theronate, and zinc L-threonate, were prepared, wherein, L-threonic acid was obtained from calcium L-threonate by strong acid type ion exchange process, calcium L-threonate or zinc L-threonate was prepared by alcohol extracting the concentrated filter liquor of the reaction of Vc, H2O2 and CaCO3 or ZnCO3, the reminder of the compounds were synthesized using alcohol extracting the concentrated solution derived from the reaction of L-threonic acid solution, prepared by double decomposition reaction of calcium L-threonate with oxalic acid, and superfluous MgO, MnCO3, Co2(OH)2CO3 and Ni2(OH)2CO3. The compositions of the compounds were determined by chemical and elemental analysis, and these compounds have the formula M(C4H7O5)2.nH2O (M = Ca, Zn, n = 0; M = Mg, Mn, Co, n = 1; M = Ni, n = 2).