Enabling the Transport Dynamics and Interfacial Stability of Porous Si Anode Via Rigid and Flexible Carbon Encapsulation for High-Energy Lithium Storage.

The stable electrode/electrolyte interface and fast electron/ion transport channel play important roles in boosting the rate performance and cycling life of lithium-ion batteries. Herein, a porous silicon/carbon composite (pSi@PC@MC) is presented by integrating hollow porous silicon (pSi) with pitch-derived carbon (PC) and dopamine-derived mesoporous carbon (MC), employing microporous zeolite as the silicon source. The finite element simulation first reveals the stress release effect of rigid and flexible carbon encapsulation on the hollow Si anode for lithium-ion storage.