Publications by authors named "Huali Zhu"

Cadmium (Cd) exposure causes oxidative damage to mitochondria, which would adversely affect rat testicular tissue. Quercetin (Que) is a natural antioxidant with anti-inflammatory, antioxidant and anti-apoptotic effects. However, the mechanism by which Que inhibits Cd-induced apoptosis of testicular cells remains unclear.

View Article and Find Full Text PDF

Background: Cadmium (Cd) is a highly toxic environmental pollutant that can enter the body through bioaccumulation. The kidney is an important target organ for Cd poisoning. Quercetin (Que) is a natural flavonoid compound with free radical scavenging and antioxidant properties.

View Article and Find Full Text PDF

Cadmium (Cd) is a highly toxic environmental pollutant. The liver is an important metabolic organ in the body and is susceptible to Cd toxicity attacks. Quercetin (Que) is a flavonoid compound with pharmacological activities of scavenging free radicals and antioxidant activity.

View Article and Find Full Text PDF

Li-rich Mn-based layered materials are considered the most promising next-generation high-energy-density cathode materials due to their high capacity, but their large irreversible capacity loss and severe voltage attenuation hinder their practical application. The limited operating voltage also makes it difficult to satisfy the increasing demand of high energy density in future applications. Inspired by the high voltage platform of Ni-rich LiNiCoMnO, we design and prepare a LiNiCoMnO (LLMO811) cathode material with increased Ni content the acrylic acid polymerization method and regulate the amounts of excess lithium of LLMO.

View Article and Find Full Text PDF

As an emerging green energy storage and conversion system, rechargeable Li-CO batteries have undergone extensive research due to their ultra-high energy density and their significant role in greenhouse gas CO conversion. However, current Li-CO batteries have some shortcomings that severely limit their large-scale application. The most critical problems involve the insulation of the discharge product LiCO and the slow decomposition kinetics, meaning that the battery generates a large overpotential and has a low cycle life, so the rational design of an efficient cathode catalyst is imperative.

View Article and Find Full Text PDF

Voltage decay during cycling is the major problem for lithium-rich layered oxide cathodes. Here, we designed Sb-doped lithium-rich layered oxides prepared by a coprecipitation-solvent thermal method, aiming to alleviate the voltage decay of lithium-rich layered oxides. The midpoint discharge voltage and specific capacity of LiNiCoMnSbO (LLMO-Sb1) demonstrate almost no decaying after 100 cycles at 1 C.

View Article and Find Full Text PDF

Nowadays, Li-CO batteries have attracted enormous interests due to their high energy density for integrated energy storage and conversion devices, superiorities of capturing and converting CO. Nevertheless, the actual application of Li-CO batteries is hindered attributed to excessive overpotential and poor lifespan. In the past decades, catalysts have been employed in the Li-CO batteries and been demonstrated to reduce the decomposition potential of the as-formed LiCO during charge process with high efficiency.

View Article and Find Full Text PDF

In this paper, we propose and demonstrate a switchable terahertz metamaterial absorber with broadband and multi-band absorption based on a simple configuration of graphene and vanadium dioxide (VO). The switchable functional characteristics of the absorber can be achieved by changing the phase transition property of VO. When VO is insulating, the device acts as a broadband absorber with absorbance greater than 90% under normal incidence from 1.

View Article and Find Full Text PDF

This study aimed to investigate the effect of naringenin (Nar) on cadmium (Cd)-induced testicular toxicity. Twenty-four male Sprague-Dawley (SD) rats aged 5 weeks were used. Rats were administered with 0.

View Article and Find Full Text PDF

To address increasingly prominent energy problems, lithium-ion batteries have been widely developed. The high-nickel type nickel-cobalt-manganese (NCM) ternary cathode material has attracted attention because of its high energy density, but it has problems such as cation mixing. To address these issues, it is necessary to start from the surface and interface of the cathode material, explore the mechanism underlying the material's structural change and the occurrence of side reactions, and propose corresponding optimization schemes.

View Article and Find Full Text PDF

Nickel-rich layered LiNiCoMnO (LiMO) is widely investigated as a promising cathode material for advanced lithium-ion batteries used in electric vehicles, and a much higher energy density in higher cut-off voltage is emergent for long driving range. However, during extensive cycling when charged to higher voltage, the battery exhibits severe capacity fading and obvious structural collapse, which leads to poor cycle stability. Herein, Sn-doping and in situ formed LiSnO nano-coating layer co-modified spherical-like LiNiCoMnO samples were successfully prepared using a facile molten salt method and demonstrated excellent cyclic properties and high-rate capabilities.

View Article and Find Full Text PDF

Cadmium (Cd), a highly toxic heavy metal, adversely affects human and animal health. Quercetin (Que) is a kind of flavonoid that can protect many tissues from the toxic effect of heavy metals. Although many studies have explored the adverse effects of cadmium on rats and other animals, the mechanism of Cd-induced testicular autophagy and the antagonistic effect of Que on cadmium remain unclear.

View Article and Find Full Text PDF

The garnet LiLaZrO (LLZO) has been widely investigated because of its high conductivity, wide electrochemical window, and chemical stability with regards to lithium metal. However, the usual preparation process of LLZO requires high-temperature sintering for a long time and a lot of mother powder to compensate for lithium evaporation. In this study submicron LiLaZrNbO (LLZNO) powder-which has a stable cubic phase and high sintering activity-was prepared using the conventional solid-state reaction and the attrition milling process, and Li stoichiometric LLZNO ceramics were obtained by sintering this powder-which is difficult to control under high sintering temperatures and when sintered for a long time-at a relatively low temperature or for a short amount of time.

View Article and Find Full Text PDF

Lithium-rich layered oxide is one of the most promising candidates for the next-generation cathode materials of high-energy-density lithium ion batteries because of its high discharge capacity. However, it has the disadvantages of uneven composition, voltage decay, and poor rate capacity, which are closely related to the preparation method. Here, 0.

View Article and Find Full Text PDF

Li-rich layered oxide cathode materials have become one of the most promising cathode materials for high specific energy lithium-ion batteries owning to its high theoretical specific capacity, low cost, high operating voltage and environmental friendliness. Yet they suffer from severe capacity and voltage attenuation during prolong cycling, which blocks their commercial application. To clarify these causes, we synthesize LiMnNiCoO (LiMnNiCoO) with high-nickel-content cathode material by a solid-sate complexation method, and it manifests a lot slower capacity and voltage attenuation during prolong cycling compared to LiMnNiCoO (LiMnNiCoO) and LiMnNiCoO (LiMnNiCoO) cathode materials.

View Article and Find Full Text PDF

Nickel-rich ternary layered oxide (LiNi80CoAlO, LNCA) cathodes are favored in many fields such as electric vehicles due to its high specific capacity, low cost, and stable structure. However, LNCA cathode material still has the disadvantages of low initial coulombic efficiency, rate capability and poor cycle performance, which greatly restricts its commercial application. To overcome this barrier, a polypyrrole (PPy) layer with high electrical conductivity is designed to coat on the surface of LNCA cathode material.

View Article and Find Full Text PDF

The high energy density lithium ion batteries are being pursued because of their extensive application in electric vehicles with a large mileage and storage energy station with a long life. So, increasing the charge voltage becomes a strategy to improve the energy density. But it brings some harmful to the structural stability.

View Article and Find Full Text PDF

The electrochemical performances and thermostability of LiNi8CoMnO is affected by temperature. High ambient temperature or irregular heat distribution accelerates the decline of LiNiCoMnO performance, shortens cathode material life. In this work, the energy storage and thermostability of the LiVO-coated LiNiCoMnO cathode material were studied for the first time by electrochemical calorimetry methode at different temperatures and rates.

View Article and Find Full Text PDF

In the family of high-performance cathode materials for lithium-ion batteries, lithium-rich layered oxides come out in front because of a high reversible capacity exceeding 250 mAh g. However, the long-term energy retention and high energy densities for lithium-rich layered oxide cathode materials require a stable structure with large surface areas. Here we propose a "bubble template" reaction to build "honeycomb-like" hollow microsphere architecture for a LiMnNiCoO cathode material.

View Article and Find Full Text PDF

Objective: To summarized the clinical features of thyroid associated ophthalmopathy patients with myasthenia gravis.

Methods: This is a retrospective case series study. The clinical data of 12 thyroid associated ophthalmopathy patients with myasthenia gravis were collected in the 416 Hospital of Nuclear Industry from Oct.

View Article and Find Full Text PDF