Coprecipitates between iron oxides and biodegradable organic acids for boosting Fenton-like catalysis under neutral pH conditions.

While the role of dissociated and complexed forms of organic acids (OAs) on Fenton-like reactions has been widely investigated, the catalytic ability and detailed mechanisms of coprecipitates between iron oxides and OAs were still obscure. Herein, coprecipitates of iron oxides with eco-friendly organic acids including maleic acid (MAA), tetrasodium-N,N-bis(carboxymethyl)-L-glutamate (GLDA), and protocatechuic acid (PCA) possessing different C/Fe molar ratios (OA-FeO, x: C/Fe molar ratios) were respectively prepared under ambient conditions. The coprecipitates exhibited eminent Fenton-like performance in removing various pollutants (e.

Nano boron carbide effectively boost Fenton-like performance of hematite mediated systems: Roles of hematite exposed facets and synergistic catalysis between Fe and B.

The inherent properties of exposed facets of iron minerals played key roles in heterogeneous reactions at the mineral interface, and the addition of co-catalysts has been elucidated to further enhance the reactions for contaminants degradation. Here, synergistic Fenton-like catalytic reactivity of different hematite dominant exposed facets ({001}, {012}, {100}, and {113}) with nano boron carbide (BC) was revealed. In 5 h, as compared with the cumulative •OH in the BC/HO system (96.

Dip2a regulates stress susceptibility in the basolateral amygdala.

JOURNAL/nrgr/04.03/01300535-202506000-00025/figure1/v/2024-08-05T133530Z/r/image-tiff Dysregulation of neurotransmitter metabolism in the central nervous system contributes to mood disorders such as depression, anxiety, and post-traumatic stress disorder. Monoamines and amino acids are important types of neurotransmitters.

The Pre- and Post-Column Derivatization on Monosaccharide Composition Analysis, a Review.

Polysaccharides, as common metabolic products in organisms, play a crucial role in the growth and development of living organisms. For humans, polysaccharides represent a class of compounds with diverse applications, particularly in the medical field. Therefore, the exploration of the monosaccharide composition and structural characteristics of polysaccharides holds significant importance in understanding their biological functions.

Inhibition Effect of Triphenylmethane Dyes for the Corrosion of Carbon Steel in CO-Saturated NaCl Corrosion Medium.

Carbon dioxide corrosion presents a significant challenge in the oil and gas field. This study simulates the corrosive environment characteristics of oil and gas fields to investigate the corrosion inhibition properties of three triphenylmethane dyes. The inhibitive performance and mechanisms of these dyes were analyzed through weight loss and electrochemical testing, revealing that crystal violet (CV) exhibited a superior inhibition effectiveness over malachite green (MG) and Fuchsine basic (FB).

PRMT5-mediated homologous recombination repair is essential to maintain genomic integrity of neural progenitor cells.

Maintaining genomic stability is a prerequisite for proliferating NPCs to ensure genetic fidelity. Though histone arginine methylation has been shown to play important roles in safeguarding genomic stability, the underlying mechanism during brain development is not fully understood. Protein arginine N-methyltransferase 5 (PRMT5) is a type II protein arginine methyltransferase that plays a role in transcriptional regulation.

Experimental and DFT insights into the adsorption mechanism of methylene blue by alkali-modified corn straw biochar.

As an efficient and cost-effective adsorbent, biochar has been widely used in the adsorption and removal of dyes. In this study, a simple NaOH-modified biochar with the pyrolysis temperature of 300 °C (NaCBC) was synthesized, characterized, and investigated for the adsorption performances and mechanisms of methylene blue (MB). NaCBC exhibited excellent MB adsorption performance with maximum removal efficiency and adsorption capacity of 99.

Effect of C Addition on the Microstructure and Fracture Properties of In Situ Laminated Nb/NbSi Composites.

//Nb and α-NbSi phases were detected. Meanwhile, NbC was observed, and the crystal forms of NbSi changed in the C-doped composites. Furthermore, micron-sized and nano-sized NbC particles were found in the Nb layer.

Microstructure and Mechanical Properties of Cast Al-Si-Cu-Mg-Ni-Cr Alloys: Effects of Time and Temperature on Two-Stage Solution Treatment and Ageing.

Ameliorating the high-temperature performance of cast Al-Si alloys used as engine components is essential. The effects of different T6 heat-treatment processes on the microstructure and mechanical properties of cast Al-Si-Cu-Mg-Ni-Cr alloys were investigated in the present study. The results demonstrate that, under the optimal solution treatment conditions of 500 °C for 2 h and 540 °C for 4 h, the T-AlFeNi phase was present in the alloy, and the roundness of primary Si and the aspect ratio of eutectic Si in the alloy reached valley values of 1.

A Nucleus Accumbens Tac1 Neural Circuit Regulates Avoidance Responses to Aversive Stimuli.

Neural circuits that control aversion are essential for motivational regulation and survival in animals. The nucleus accumbens (NAc) plays an important role in predicting aversive events and translating motivations into actions. However, the NAc circuits that mediate aversive behaviors remain elusive.

Facile preparation of coprecipitates between iron oxides and dissolved organic matter for efficient Fenton-like degradation of norfloxacin.

As two important components of dissolved organic matter (DOM), dissolved black carbon (DBC) and humic acid (HA) possess different chemical and structural properties, which might influence their activities like metal complexation and mediating electron transfer. In this study, a series of coprecipitates of iron oxides (FeO) and DOM (HA or DBC) having different C/Fe molar ratios (0.2-3.

Superhydrophobic Biological Fluid-Repellent Surfaces: Mechanisms and Applications.

Superhydrophobic biological fluid-repellent surfaces (SBFRSs) have attracted great attention in the treatment of blood and urine-related diseases because of their unique wettability and compatibility, which creates a new path for the development of medical apparatus and instruments, and are expected to create advances in various fields. Here, this review provides an up-to-date summary of research progress on the repellent mechanism and application of SBFRSs. The underlying physical and chemical principles for designing superhydrophobic surfaces are first introduced.

Dysregulation of AMPK-mTOR signaling leads to comorbid anxiety in Dip2a KO mice.

Autism is often comorbid with other psychiatric disorders. We have previously shown that Dip2a knockout (KO) induces autism-like behaviors in mice. However, the role of Dip2a in other psychiatric disorders remains unclear.

A Novel Netrin-1-Derived Peptide Enhances Protection against Neuronal Death and Mitigates of Intracerebral Hemorrhage in Mice.

It has been reported that Netrin-1 is involved in neuroprotection following injury to the central nervous system. However, the minimal functional domain of Netrin-1 which can preserve the neuroprotection but avoid the major side effects of Netrin remains elusive. Here, we investigated the neuroprotective effect of a peptide E1 derived from Netrin-1's EGF3 domain (residues 407-422).

DIP2A is involved in SOD-mediated antioxidative reactions in murine brain.

Autism spectrum disorders (ASDs) are highly associated with oxidative stress. We have recently shown that Disconnected-interacting protein homolog 2 A (DIP2A) functions in ASD pathophysiology by regulating cortactin acetylation for spine development and synaptic transmission. However, its role is not fully understood in the context of its abundant expression in mitochondria.

Synergistic catalytic Fenton-like degradation of sulfanilamide by biosynthesized goethite-reduced graphene oxide composite.

A series of goethite (Gt)-graphene (rGO) composites (Gt-rGO) having different rGO contents (2%-10%) was biologically prepared under mild conditions with Acidovorax sp. BoFeN1 and exhibited comparable or even higher catalytic efficiencies upon sulfonamides degradation than most known chemically synthesized catalysts. Pseudo-first-order rate constant of sulfanilamide degradation (60 μM, 0.

Goethite-humic acid coprecipitate mediated Fenton-like degradation of sulfanilamide: The role of coprecipitated humic acid in accelerating Fe(III)/Fe(II) cycle and degradation efficiency.

While extensive studies found that dissociative and iron mineral-adsorbed humic acid (HA) could either stimulate or inhibit Fenton-like processes, little was known about the influence of iron mineral-coprecipitated HA on Fenton-like reactions. Here, goethite and HA (Gt-HA) coprecipitates having different C:Fe molar ratios (C:Fe = 0.16-0.

Nucleus Accumbens Tac1-Expressing Neurons Mediate Stress-Induced Anhedonia-like Behavior in Mice.

Major depressive disorder (MDD) presents with two primary symptoms: depressed mood and anhedonia, which suggests that distinct neuronal circuits may regulate MDD. However, the underlying circuits of these individual symptoms linked to depression remain elusive. Herein, we identify a discrete circuit of tachykinin precursor 1 (Tac1)-expressing neurons in the nucleus accumbens (NAc) lateral shell, which project to ventral pallidum and contribute to stress-induced anhedonia-like behavior.

Myosin X Interaction with KIF13B, a Crucial Pathway for Netrin-1-Induced Axonal Development.

Myosin X (Myo X) transports cargos to the tips of filopodia for cell adhesion, migration, and neuronal axon guidance. Deleted in Colorectal Cancer (DCC) is one of the Myo X cargos that is essential for Netrin-1-regulated axon pathfinding. The function of Myo X in axon development and the underlying mechanisms remain elusive.

Acceleration of goethite-catalyzed Fenton-like oxidation of ofloxacin by biochar.

While carbon materials have been well studied to stimulate the homogeneous Fenton-like processes, little was known about their impacts on iron mineral-catalyzed heterogeneous Fenton-like reactions. Here, it was found that biochar prepared at 300 °C or 600 °C (BC300 or BC600) greatly stimulated the degradation of ofloxacin (OFX) in a goethite (Gt)-mediated Fenton-like system. In 4 h, while only 38.

Bactericidal and antifouling electrospun PVA nanofibers modified with a quaternary ammonium salt and zwitterionic sulfopropylbetaine.

Bacterial adhesion and colonization on material surfaces have attracted great attention due to their potential threat to human health. Combining bactericidal and antifouling functions has been confirmed as an optimal strategy to prevent microbial infection. In this work, biodegradable electrospun polyvinyl alcohol (PVA) nanofibers were chosen due to its high specific area and abundant reactive hydroxyl groups.

DIP2B Interacts With α-Tubulin to Regulate Axon Outgrowth.

Axonal development is essential to the establishment of neuronal morphology and circuitry, although the mechanisms underlying axonal outgrowth during the early developmental stages remain unclear. Here, we showed that the conserved disco-interacting protein B (DIP2B) which consists of a DMAP1 domain and a crotonobetaine/carnitine CoA ligase (Caic) domain, is highly expressed in the excitatory neurons of the hippocampus. DIP2B knockout led to excessive axonal outgrowth but not polarity at an early developmental stage.