Iodine-Doped Hollow Carbon Nanocages without Templates Strategy for Boosting Zinc-Ion Storage by Nucleophilicity.

Zn-ion hybrid supercapacitors (ZHCs) combining merits of battery-type and capacitive electrodes are considered to be a prospective candidate in energy storage systems. Tailor-made carbon cathodes with high zincophilicity and abundant physi/chemisorption sites are critical but it remains a great challenge to achieve both features by a sustainable means. Herein, a hydrogen-bonding interaction-guided self-assembly strategy is presented to prepare iodine-doped carbon nanocages without templates for boosting zinc-ion storage by nucleophilicity.

Cross-linking and self-assembly synthesis of tannin-based carbon frameworks cathode for Zn-ion hybrid supercapacitors.

Carbon frameworks with well-developed porosity present broad application prospects in energy-related materials, and green preparation still face challenges. Herein, the tannins-derived framework-like carbon material is obtained by cross-linking and self-assembly strategy.The phenolic hydroxyl and quinones in tannin cross-linking react with the amine groups in the methenamine by simple stirring, which drives the self-assembly of tannins and methenamine,contributing to the reaction products being precipitated in solution as aggregates with framework-like structure.

Pyrolysis of furfural residues: Property and applications of the biochar.

Furfural residue (FR) is a solid waste generated during the production of furfural from corn cobs. The chemical energy and material potential of FR can be potentially recovered via pyrolysis. In this study, the pyrolysis of FR at the temperature ranging from 350 to 650 °C at the varied heating rate was investigated, aiming to understand the characteristics of the pyrolysis products.

Synergy of Oxygen Vacancies and Acid Sites on N-Doped WO Nanobelts for Efficient C-C Coupling Synthesis of Benzoin Isopropyl Ether.

The surface property of a photocatalyst, including surface acid sites and oxygen vacancies, plays a pivotal role in photocatalytic organic synthesis reactions. Benzoin isopropyl ether (BIE) is usually produced via polycondensation of benzaldehyde and catalyzed with highly toxic . Here, we report a green photocatalytic approach for the selective synthesis of BIE over WO driven by a green-light-emitting diode.

Hydrogen-bonded frameworks crystals-assisted synthesis of flower-like carbon materials with penetrable meso/macropores from heavy fraction of bio-oil for Zn-ion hybrid supercapacitors.

The application of biomass-based carbon materials in electrode materials are usually subject to their deficient adsorption sites as well as sluggish diffusion of electrolyte ions. Herein, flower-like carbons are obtained from the heavy fraction of bio-oil with the auxiliary of Hydrogen-bonded frameworks (HOFs) crystals. During the co-carbonization of the both, the HOFs crystals are removed on account of its poor stability, which directs the formation of flower-like morphology and generates the penetrable meso/macropores across petal-like carbon nanosheets.

In Situ Electrochemical Fabrication of Ultrasmall Ru-Based Nanoparticles for Robust NH Oxidation.

Ultrasmall Ru nanoparticles is expected as a potential alternative to Pt for efficient hydrazine oxidation (HzOR). However, preparation of ultrasmall and well-distributed Ru nanoparticles usually suffered from the steps of modification of supports, coordination, reduction with strong reducing reagents (e.g.

Boosting Oxygen Electroreduction over Strained Silver.

Manipulating the strain effect of Ag without any foreign metals to boost its intrinsic oxygen reduction reaction (ORR) activity is intriguing, but it remains a challenge. Herein, we developed a class of Ag-based electrocatalysts with tunable strain structures for efficient ORR via ligand-assisted competitive decomposition of Ag-organic complexes (AgOCs). Benefiting from the superior coordination capability, 4,4'-bipyridine as a ligand triggered a stronger competition with NaBH for Ag ions during reduction-induced decomposition of AgOCs in comparison with the counterparts of the pyrazine ligand and the NO anion, which moderately modulated the compressive strain structure to upshift the d-band center of the catalyst and increase the electron density of Ag.

Mimicking Hydrazine Dehydrogenase for Efficient Electrocatalytic Oxidation of NH by Fe-NC.

Pursuing nonprecious doped carbon with Pt-like electrocatalytic NH oxidation activity for hydrazine fuel cells (HzFCs) remains a challenge. Herein, we present a Fe/N-doped carbon (Fe-NC) catalyst with mesopore-rich channel and highly dispersed Fe-N sites incorporated in N-doped carbon, as an analogue of hydrazine dehydrogenase (HDH), showing the structure-dependent activity for electrocatalytic oxidation of NH. The maximal turnover frequency of the NH oxidation reaction (HzOR) over the Fe-N sites (62870 h) is 149-fold that over the pyridinic-N sites of N-doped carbon.

Oxidase-Inspired Selective 2e/4e Reduction of Oxygen on Electron-Deficient Cu.

Development of low-cost and efficient (electro)catalysts with tunable 2e/4e oxygen reduction reaction (ORR) selectivity toward energy conversion, biomimetic catalysis, and biosensing has attracted growing interest. Herein, we reported that carbon nanohybrids with O- or N-coordinated Cu (Cu-OC or Cu-NC) showed superior activity for 2e and 4e electrocatalytic ORR with selectivities of 84.0% and 97.

Fe3O4@Carbon Nanosheets for All-Solid-State Supercapacitor Electrodes.

Fe3O4@carbon nanosheet composites were synthesized using ammonium ferric citrate as the Fe3O4/carbon precursor and graphene oxide as the structure-directing agent under a hydrothermal process. The surface chemical compositions, pore structures, and morphology of the composite were analyzed and characterized by nitrogen adsorption isotherms, TG analysis, FT-IR, X-ray photoelectron energy spectrum, transmission electron microscopy, and scanning electron microscopy. The composites showed excellent specific capacitance of 586 F/g, 340 F/g at 0.

Carbon Nanosheets: Synthesis and Application.

Carbon nanosheets (CNSs) with tunable sizes, morphologies, and pore structures have been synthesized through several chemical routes. Graphitized CNSs have been synthesized through exfoliation, chemical vapor deposition, or high-temperature carbonization. Porous CNSs have been synthesized by using various methods, including pyrolysis, self-assembly, or a solvothermal method in connection with carbonization.