Spatioselective Occlusion of Copolymer Nanoparticles within Calcite Crystals Generates Organic-Inorganic Hybrid Materials with Controlled Internal Structures.

Efficient occlusion of particulate additives into a single crystal has garnered an ever-increasing attention in materials science because it offers a counter-intuitive yet powerful platform to make crystalline nanocomposite materials with emerging properties. However, precisely controlling the spatial distribution of the guest additives within a host crystal remains highly challenging. We herein demonstrate a unique, straightforward method to engineer the spatial distribution of copolymer nanoparticles within calcite (CaCO) single crystals by judiciously adjusting initial [Ca] concentration used for the calcite precipitation.

Magnetically Reusable and Well-dispersed Nanoparticles for Oxygen Detection in Water.

In this study, we aimed to synthesize magnetically well-dispersed nanosensors for detecting dissolved oxygen (DO) in water, and explore their biological applications. Firstly, we synthesized two kinds of magnetic nanoparticle with average sizes of approximately 82 nm by one-step emulsion polymerization: polystyrene magnetic nanoparticles (FeO@Os1-PS) and polymethylmethacrylate magnetic nanoparticles (FeO@Os1-PMMA). Both types of nanoparticle present good dispersibility and fluorescence stability.

Paralinguistic singing attribute recognition using supervised machine learning for describing the classical tenor solo singing voice in vocal pedagogy.

Humans can recognize someone's identity through their voice and describe the timbral phenomena of voices. Likewise, the singing voice also has timbral phenomena. In vocal pedagogy, vocal teachers listen and then describe the timbral phenomena of their student's singing voice.

Association of long-term inhalation of caffeine-sodium benzoate with coronary heart disease in men.

Objective: A possible correlation between caffeine and coronary heart disease (CHD) is controversial. The objective of this study was to explore the effect of long-term inhalation of caffeine-sodium benzoate (CSB) on the development of CHD in men, the severity of coronary artery lesions and the possible contributing effects of smoking.

Materials: A retrospective analysis was performed on 2,001 consecutive men who underwent selective coronary angiography.

Easily Synthesized Polyaniline@Cellulose Nanowhiskers Better Tune Network Structures in Ag-Based Adhesives: Examining the Improvements in Conductivity, Stability, and Flexibility.

It is essential to develop a novel and versatile strategy for constructing electrically conductive adhesives (ECAs) that have superior conductivity and high mechanical properties. In this work, easily synthesized polyaniline@cellulose (PANI@CNs) nanowhiskers with a high aspect ratio and excellent solubility in 1,4-dioxane were prepared and added to conventional Ag-containing adhesives. A small amount of PANI@CNs can dramatically tune the structure of the ECAs' conductive network and significantly improve the conductivity of the ECAs.