Overcoming metals redox rate limitations in spinel oxide-driven Fenton-like reactions via synergistic heteroatom doping and carbon anchoring for efficient micropollutant removal.

The transition metals redox rate limitations of spinel oxides during Fenton-like reactions hinder its efficient and sustainable treatment of actual wastewater. Herein, we propose to optimize the electronic structure of Co-Mn spinel oxide (CM) via sulfur doping and carbon matrix anchoring synergistically, enhancing the radicals-nonradicals Fenton-like processes for efficient water decontamination. Activating peroxymonosulfate (PMS) with optimised spinel oxide (CMSAC) achieved near-complete removal of ofloxacin (10 mg/L) within 6 min, showing 8.

Leachate from municipal solid waste landfills: A neglected source of microplastics in the environment.

Over the past decade or so, microplastics (MPs) have received increasing attention due to their ubiquity and potential risk to the environment. Waste plastics usually end up in landfills. These plastics in landfills undergo physical compression, chemical oxidation, and biological decomposition, breaking down into MPs.

Target-prepared sludge biochar-derived synergistic Mn and N/O induces high-performance periodate activation for reactive iodine radicals generation towards ofloxacin degradation.

Converting waste activated sludge into catalysts for the removal of antibiotics in water fulfils the dual purpose of waste-to-resource and hazardous pollution elimination. In this study, sludge-derived biochar (SDB) for efficient periodate (PI) activation was first prepared via one-step pyrolysis of potassium permanganate-polyhexamethylenebiguanide conditioned sludge without additional modification. The SDB (750 °C)-PI system degraded 100% ofloxacin (OFL, 41.

Unveiling the occurrence, distribution, removal, and environmental impacts of 65 emerging contaminants in neglected fresh leachate from municipal solid waste incineration plants.

Emerging contaminants (ECs) are commonly found in environmental media. Yet leachate from municipal solid waste incineration plants (MSWIPs), which can serve as a reservoir for various contaminants, including ECs, has received little investigation. To address this gap, 65 ECs were analyzed in the fresh leachate and biological effluent from three major MSWIPs in Shanghai.

Factors affecting the durability of dimethyl dithiocarbamate-stabilized air pollution control (APC) residues derived from municipal solid waste incineration.

Sodium dimethyl dithiocarbamate (SDD) is widely used for stabilizing heavy metals to minimize pollution from air pollution control (APC) residues derived from municipal solid waste incineration. However, the effect of environmental conditions on heavy metal leaching from SDD-stabilized APC residues remains unknown. Therefore, this study aimed to evaluate the durability of SDD-stabilized APC residues and determine the relationship between heavy metal leaching and environmental factors, including pH, temperature, and oxygen.

Distribution, removal and ecological risk assessment of antibiotics in leachate from municipal solid waste incineration plants in Shanghai, China.

Leachate from Municipal Solid Waste (MSW) incineration plants contains multiple antibiotics. However, current knowledge of antibiotics in such leachate is very limited compared to landfill leachate. In this study, the distribution, removal and ecological risks of 8 sulfonamides (SAs), 4 quinolones (FQs), and 4 macrolides (MLs) antibiotics in leachate from three MSW incineration plants in Shanghai were investigated.

A sustainable reuse strategy of converting waste activated sludge into biochar for contaminants removal from water: Modifications, applications and perspectives.

Conversion of sewage sludge to biochar for contaminants removal from water achieves the dual purpose of solid waste reuse and pollution elimination, in line with the concept of circular economy and carbon neutrality. However, the current understanding of sludge-derived biochar (SDB) for wastewater treatment is still limited, with a lack of summary regarding the effect of modification on the mechanism of SDB adsorption/catalytic removal aqueous contaminants. To advance knowledge in this aspect, this paper systematically reviews the recent studies on the use of (modified) SDB as adsorbents and in persulfate-based advanced oxidation processes (PS-AOPs) as catalysts for the contaminants removal from water over the past five years.

A review of pristine and modified biochar immobilizing typical heavy metals in soil: Applications and challenges.

In recent years, the application of biochar in the remediation of heavy metals (HMs) contaminated soil has received tremendous attention globally. We reviewed the latest research on the immobilization of soil HMs by biochar almost in the last 5 years (until 2021). The methods, effects and mechanisms of biochar and modified biochar on the immobilization of typical HMs in soil have been systematically summarized.

Mechanism of cadmium removal from soil by silicate composite biochar and its recycling.

Biochar added to the soil is generally difficult to separate. In order to solve the problem of separating biochar from soil, this paper applies a hydraulic silicate gel material to the preparation of biochar. Non-magnetic silicate bonded biochar (SBC) and magnetic silicate bonded biochar (MSBC) with hydraulic properties were prepared.

Contributions and mechanisms of components in modified biochar to adsorb cadmium in aqueous solution.

Recently, researchers have carried out a large number of studies on the adsorption of heavy metals by modified biochar, but there have been fewer explorations of the contributions and mechanisms of components in biochar composites on heavy metals adsorption. In this paper, the biochar was modified by Fe/Fe and NaOH, and a further analysis of the adsorption of cadmium on the new biochar was conducted. It was found that (1) the adsorption capacity for cadmium of the modified biochar (M85) was 406.

Preparation of biochar with high absorbability and its nutrient adsorption-desorption behaviour.

To study the formation of biochar with high absorbability, experiments were carried out at different carbonization temperature (300, 400, 600, and 800 °C) and under different carbonization atmosphere (activating gases (steam and CO) and inert gas (N)) to prepare biochar. In this paper, the effects of the carbonization atmosphere on the biochar pore structure were studied, and the influence of the biochar pore structure on the adsorption-desorption behaviour of nutrients (NH-N, NO-N, P, and K) was investigated. Experimental results: (1) The activating gases (steam and CO) can catalytically crack activated carbon atoms and tar blocking the biochar pores at high temperatures (T > 600 °C), and the activating gas promotes the formation of microporous biochar (d < 2 nm).